Pregled bibliografske jedinice broj: 1788
Comparative Study of Homogeneous Hydrogenation of D-Glucose and D-Mannose Catalyzed by Water Soluble [Ru(tri(m-sulfophenyl)phosphine)] Complexes
Comparative Study of Homogeneous Hydrogenation of D-Glucose and D-Mannose Catalyzed by Water Soluble [Ru(tri(m-sulfophenyl)phosphine)] Complexes // Journal of molecular catalysis. A, Chemical, 110 (1996), 3; 189-193 doi:10.1016/1381-1169(96)00088-X (međunarodna recenzija, članak, znanstveni)
CROSBI ID: 1788 Za ispravke kontaktirajte CROSBI podršku putem web obrasca
Naslov
Comparative Study of Homogeneous Hydrogenation of D-Glucose and D-Mannose Catalyzed by Water Soluble [Ru(tri(m-sulfophenyl)phosphine)] Complexes
Autori
Kolarić, Snježana ; Šunjić, Vitomir
Izvornik
Journal of molecular catalysis. A, Chemical (1381-1169) 110
(1996), 3;
189-193
Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni
Ključne riječi
(sulfophenyl)phosphine derivatives ; Phosphine derivatives. Ruthenium ; Formiates ; Sodium ; Ammonium ; Hydrogenation
Sažetak
Homogeneous hydrogenation of two epimeric aldoses, D-glucose (D-Glc) and D-mannose (D-Man) was performed in water, with molecular hydrogen and by transfer hydrogenation catalyzed by [Ru-TPPTS] complex (TPPTS=trisodium salt of tri(m-sulfophenyl)phosphine). Both method proved effective, and revealed D-Man as more reactive aldose. Hydrogen transfer has been studied with various hydrogen donors ; the most effective, hut highly pH-dependent system has been found in Et(3)N/formic acid (azeotropic mixture 2:5) as the source of hydrogen.
Izvorni jezik
Engleski
Znanstvena područja
Kemija
Citiraj ovu publikaciju:
Časopis indeksira:
- Current Contents Connect (CCC)
- Web of Science Core Collection (WoSCC)
- Science Citation Index Expanded (SCI-EXP)
- SCI-EXP, SSCI i/ili A&HCI
- Scopus
