Pregled bibliografske jedinice broj: 1787
Comparative Study of C(2) Epimerization of D-Glucose and D-Mannose Catalyzed by Water Soluble Organometallic Complexes with Nitrogen Ligands
Comparative Study of C(2) Epimerization of D-Glucose and D-Mannose Catalyzed by Water Soluble Organometallic Complexes with Nitrogen Ligands // Journal of molecular catalysis. A, Chemical, 110 (1996), 3; 181-188 doi:10.1016/1381-1169(96)00089-1 (međunarodna recenzija, članak, znanstveni)
CROSBI ID: 1787 Za ispravke kontaktirajte CROSBI podršku putem web obrasca
Naslov
Comparative Study of C(2) Epimerization of D-Glucose and D-Mannose Catalyzed by Water Soluble Organometallic Complexes with Nitrogen Ligands
Autori
Kolarić, Snježana ; Šunjić, Vitomir
Izvornik
Journal of molecular catalysis. A, Chemical (1381-1169) 110
(1996), 3;
181-188
Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni
Ključne riječi
Ethylenamines ; Copper ; Nickel ; Cobalt ; Cadmium ; Epimerization ; Isomerization
Sažetak
Epimerization of D-glucose and D-mannose, catalyzed by the water soluble complexes of Cu(II), Ni(II), Co(II) and Cd(II) with bisnitrogen ligands 4-7, and by Mo(VI) complexes prepared in situ from ammonium heptamolybdate (AHM) with ligands 4-9 is compared. All examined complexes exhibit lower catalytic activity than AHM ; strong coordination of the ligands by both (N, O) heteroatoms to metal ions, presumably affords catalytically less active species. Some free ligands and their metal (II) complexes catalyze both C(2) epimerization and isomerization of aldoses to D-fructose.
Izvorni jezik
Engleski
Znanstvena područja
Kemija
Citiraj ovu publikaciju:
Časopis indeksira:
- Current Contents Connect (CCC)
- Web of Science Core Collection (WoSCC)
- Science Citation Index Expanded (SCI-EXP)
- SCI-EXP, SSCI i/ili A&HCI
- Scopus
