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Pregled bibliografske jedinice broj: 167698

Synthesis and crystal structure of 2[(Ta6Cl12)Cl3(n-BuCN)3]·[(Ta6Cl12)Cl4(n-BuCN)2]·n-BuCN. The first cluster compound containing [Ta6Cl12]3+ and [Ta6Cl12]4+ cores

Planinić, Pavica; Rastija, Vesna; Perić, Berislav; Giester, Gerald; Brničević, Nevenka
Synthesis and crystal structure of 2[(Ta6Cl12)Cl3(n-BuCN)3]·[(Ta6Cl12)Cl4(n-BuCN)2]·n-BuCN. The first cluster compound containing [Ta6Cl12]3+ and [Ta6Cl12]4+ cores // Comptes rendus. Chimie, 8 (2005), 11-12; 1766-1773 doi:10.1016/j.crci.2005.02.026 (međunarodna recenzija, članak, znanstveni)

CROSBI ID: 167698 Za ispravke kontaktirajte CROSBI podršku putem web obrasca

Naslov
Synthesis and crystal structure of 2[(Ta6Cl12)Cl3(n-BuCN)3]·[(Ta6Cl12)Cl4(n-BuCN)2]·n-BuCN. The first cluster compound containing [Ta6Cl12]3+ and [Ta6Cl12]4+ cores

Autori
Planinić, Pavica ; Rastija, Vesna ; Perić, Berislav ; Giester, Gerald ; Brničević, Nevenka

Izvornik
Comptes rendus. Chimie (1631-0748) 8 (2005), 11-12; 1766-1773

Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni

Ključne riječi
hexanuclear tantalum cluster ; mixed-charge cluster ; crystal structure ; coordinated n-butyl cyanide

Sažetak
By partial oxidation of a solution of (Ta6Cl12)Cl2·6 EtOH in n-butyl cyanide (n-BuCN) reddish crystals of the title compound were formed. The compound crystallizes in the monoclinic C2/m space group. The double salt components [(Ta6Cl12)Cl3(n-BuCN)3] and [(Ta6Cl12)Cl4(n-BuCN)2] are of Cs and C2h symmetry, respectively. The structure consists of layers formed by the intergrown one-dimensional chains of the different cluster components. The crystal structure analysis and UV spectra revealed differently charged cluster entities, namely [Ta6Cl12]3+ and [Ta6Cl12]4+ in [(Ta6Cl12)Cl3(n-BuCN)3] and [(Ta6Cl12)Cl4(n-BuCN)2], respectively.

Izvorni jezik
Engleski

Znanstvena područja
Kemija



POVEZANOST RADA

Projekti:
0098066

Ustanove:
Institut "Ruđer Bošković", Zagreb

Profili:

Avatar Url Berislav Perić (autor)

Avatar Url Nevenka Brničević (autor)

Avatar Url Vesna Rastija (autor)

Avatar Url Pavica Planinić (autor)

Poveznice na cjeloviti tekst rada:

doi www.sciencedirect.com

Citiraj ovu publikaciju:

Planinić, Pavica; Rastija, Vesna; Perić, Berislav; Giester, Gerald; Brničević, Nevenka
Synthesis and crystal structure of 2[(Ta6Cl12)Cl3(n-BuCN)3]·[(Ta6Cl12)Cl4(n-BuCN)2]·n-BuCN. The first cluster compound containing [Ta6Cl12]3+ and [Ta6Cl12]4+ cores // Comptes rendus. Chimie, 8 (2005), 11-12; 1766-1773 doi:10.1016/j.crci.2005.02.026 (međunarodna recenzija, članak, znanstveni)
Planinić, P., Rastija, V., Perić, B., Giester, G. & Brničević, N. (2005) Synthesis and crystal structure of 2[(Ta6Cl12)Cl3(n-BuCN)3]·[(Ta6Cl12)Cl4(n-BuCN)2]·n-BuCN. The first cluster compound containing [Ta6Cl12]3+ and [Ta6Cl12]4+ cores. Comptes rendus. Chimie, 8 (11-12), 1766-1773 doi:10.1016/j.crci.2005.02.026.
@article{article, author = {Planini\'{c}, Pavica and Rastija, Vesna and Peri\'{c}, Berislav and Giester, Gerald and Brni\v{c}evi\'{c}, Nevenka}, year = {2005}, pages = {1766-1773}, DOI = {10.1016/j.crci.2005.02.026}, keywords = {hexanuclear tantalum cluster, mixed-charge cluster, crystal structure, coordinated n-butyl cyanide}, journal = {Comptes rendus. Chimie}, doi = {10.1016/j.crci.2005.02.026}, volume = {8}, number = {11-12}, issn = {1631-0748}, title = {Synthesis and crystal structure of 2[(Ta6Cl12)Cl3(n-BuCN)3]·[(Ta6Cl12)Cl4(n-BuCN)2]·n-BuCN. The first cluster compound containing [Ta6Cl12]3+ and [Ta6Cl12]4+ cores}, keyword = {hexanuclear tantalum cluster, mixed-charge cluster, crystal structure, coordinated n-butyl cyanide} }
@article{article, author = {Planini\'{c}, Pavica and Rastija, Vesna and Peri\'{c}, Berislav and Giester, Gerald and Brni\v{c}evi\'{c}, Nevenka}, year = {2005}, pages = {1766-1773}, DOI = {10.1016/j.crci.2005.02.026}, keywords = {hexanuclear tantalum cluster, mixed-charge cluster, crystal structure, coordinated n-butyl cyanide}, journal = {Comptes rendus. Chimie}, doi = {10.1016/j.crci.2005.02.026}, volume = {8}, number = {11-12}, issn = {1631-0748}, title = {Synthesis and crystal structure of 2[(Ta6Cl12)Cl3(n-BuCN)3]·[(Ta6Cl12)Cl4(n-BuCN)2]·n-BuCN. The first cluster compound containing [Ta6Cl12]3+ and [Ta6Cl12]4+ cores}, keyword = {hexanuclear tantalum cluster, mixed-charge cluster, crystal structure, coordinated n-butyl cyanide} }

Časopis indeksira:


  • Current Contents Connect (CCC)
  • Web of Science Core Collection (WoSCC)
    • Science Citation Index Expanded (SCI-EXP)
    • SCI-EXP, SSCI i/ili A&HCI
  • Scopus

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