Pregled bibliografske jedinice broj: 16401
Tuning Dimensionality in Low-Dimensional Electronic Materials
Tuning Dimensionality in Low-Dimensional Electronic Materials // Chemical physics letters, 289 (1998), 5/6; 559-566 doi:10.1016/S0009-2614(98)00476-X (međunarodna recenzija, članak, znanstveni)
CROSBI ID: 16401 Za ispravke kontaktirajte CROSBI podršku putem web obrasca
Naslov
Tuning Dimensionality in Low-Dimensional Electronic Materials
Autori
Strouse, G.F. ; Scott, B. ; Swanson, B.I. ; Saxena, A. ; Batistić, Ivo ; Gammel, J.T. ; Bishop, A.R.
Izvornik
Chemical physics letters (0009-2614) 289
(1998), 5/6;
559-566
Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni
Ključne riječi
low-dimensional materials ; halogen-bridged transition-metal charge-transfer complex
Sažetak
We demonstrate how dimensionality can be tuned in complex low-dimensional electronic materials via small perturbations in competing molecular forces. The delicate balance between molecular level forces on observed dimensionality in materials is illustrated by the 1-d to 3-d structural reorganization following deuteration of the ancillary ligands in the halogen-bridged transition-metal charge-transfer complex [Pt(en)(2)I-2][Pt(en)(2)]I-2 (PtI) where en denotes ethylenediamine. Specifically, the impact of competing forces on dimensionality is clearly demonstrated by the temperature-dependent phase transitions in perdeuterated PtI (D-PtI), where small changes in inter-and intra-sheet interactions drive mesoscopic structural changes.
Izvorni jezik
Engleski
Znanstvena područja
Fizika
POVEZANOST RADA
Citiraj ovu publikaciju:
Časopis indeksira:
- Current Contents Connect (CCC)
- Web of Science Core Collection (WoSCC)
- Science Citation Index Expanded (SCI-EXP)
- SCI-EXP, SSCI i/ili A&HCI
- Scopus
