Pretraga

Pretražite po imenu i prezimenu autora, mentora, urednika, prevoditelja

Napredna pretraga

Pregled bibliografske jedinice broj: 147460

An in situ microscopic spectroelectrochemical study of a three-phase electrode where an ion transfer at the water|nitrobenzene interface is coupled to an electron transfer at the interface ITO|nitrobenzene

Komorsky-Lovrić, Šebojka; Mirčeski, Valentin; Kabbe, Christian; Scholz, Fritz
An in situ microscopic spectroelectrochemical study of a three-phase electrode where an ion transfer at the water|nitrobenzene interface is coupled to an electron transfer at the interface ITO|nitrobenzene // Journal of electroanalytical chemistry (1992), 566 (2004), 371-377 doi:10.1016/j.jelechem.2003.11.048 (međunarodna recenzija, članak, znanstveni)

CROSBI ID: 147460 Za ispravke kontaktirajte CROSBI podršku putem web obrasca

Naslov
An in situ microscopic spectroelectrochemical study of a three-phase electrode where an ion transfer at the water|nitrobenzene interface is coupled to an electron transfer at the interface ITO|nitrobenzene

Autori
Komorsky-Lovrić, Šebojka ; Mirčeski, Valentin ; Kabbe, Christian ; Scholz, Fritz

Izvornik
Journal of electroanalytical chemistry (1992) (1572-6657) 566 (2004); 371-377

Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni

Ključne riječi
three-phase junction ; voltammetry ; ion transfer ; electron transfer

Sažetak
The coupled electron and ion transfer was studied at a three-phase arrangement where decamethylferrocene was dissolved in a droplet of nitrobenzene that was sandwiched between an optically transparent ITO electrode and a glass plate. The sandwiched droplet was surrounded by an aqueous electrolyte solution in which the auxiliary and the reference electrodes were positioned. The oxidation of decamethylferrocene was followed by in situ spectroscopy with the help of a spectrometer interfaced to an optical microscope. The fast progression of the reaction starting at the three-phase junction and advancing towards the middle of the droplet is explained on the basis of a simplified model that assumes a progressing activation of the working electrode | nitrobenzene interface due to the ingress of transferred anions and decrease of ohmic resistance inside the nitrobenzene phase.

Izvorni jezik
Engleski

Znanstvena područja
Kemija



POVEZANOST RADA

Projekti:
0098123

Ustanove:
Institut "Ruđer Bošković", Zagreb

Profili:

Avatar Url Šebojka Komorsky-Lovrić (autor)

Poveznice na cjeloviti tekst rada:

doi www.sciencedirect.com

Citiraj ovu publikaciju:

Komorsky-Lovrić, Šebojka; Mirčeski, Valentin; Kabbe, Christian; Scholz, Fritz
An in situ microscopic spectroelectrochemical study of a three-phase electrode where an ion transfer at the water|nitrobenzene interface is coupled to an electron transfer at the interface ITO|nitrobenzene // Journal of electroanalytical chemistry (1992), 566 (2004), 371-377 doi:10.1016/j.jelechem.2003.11.048 (međunarodna recenzija, članak, znanstveni)
Komorsky-Lovrić, Š., Mirčeski, V., Kabbe, C. & Scholz, F. (2004) An in situ microscopic spectroelectrochemical study of a three-phase electrode where an ion transfer at the water|nitrobenzene interface is coupled to an electron transfer at the interface ITO|nitrobenzene. Journal of electroanalytical chemistry (1992), 566, 371-377 doi:10.1016/j.jelechem.2003.11.048.
@article{article, author = {Komorsky-Lovri\'{c}, \v{S}ebojka and Mir\v{c}eski, Valentin and Kabbe, Christian and Scholz, Fritz}, year = {2004}, pages = {371-377}, DOI = {10.1016/j.jelechem.2003.11.048}, keywords = {three-phase junction, voltammetry, ion transfer, electron transfer}, journal = {Journal of electroanalytical chemistry (1992)}, doi = {10.1016/j.jelechem.2003.11.048}, volume = {566}, issn = {1572-6657}, title = {An in situ microscopic spectroelectrochemical study of a three-phase electrode where an ion transfer at the water|nitrobenzene interface is coupled to an electron transfer at the interface ITO|nitrobenzene}, keyword = {three-phase junction, voltammetry, ion transfer, electron transfer} }
@article{article, author = {Komorsky-Lovri\'{c}, \v{S}ebojka and Mir\v{c}eski, Valentin and Kabbe, Christian and Scholz, Fritz}, year = {2004}, pages = {371-377}, DOI = {10.1016/j.jelechem.2003.11.048}, keywords = {three-phase junction, voltammetry, ion transfer, electron transfer}, journal = {Journal of electroanalytical chemistry (1992)}, doi = {10.1016/j.jelechem.2003.11.048}, volume = {566}, issn = {1572-6657}, title = {An in situ microscopic spectroelectrochemical study of a three-phase electrode where an ion transfer at the water|nitrobenzene interface is coupled to an electron transfer at the interface ITO|nitrobenzene}, keyword = {three-phase junction, voltammetry, ion transfer, electron transfer} }

Časopis indeksira:


  • Current Contents Connect (CCC)
  • Web of Science Core Collection (WoSCC)
    • Science Citation Index Expanded (SCI-EXP)
    • SCI-EXP, SSCI i/ili A&HCI
  • Scopus

Citati:

    Altmetrijski pokazatelji:


    Podijeli:





    Contrast
    Increase Font
    Decrease Font
    Dyslexic Font
    CROSBI koristi kolačiće (cookies) kako bi poboljšao funkcionalnost stranice.