Pregled bibliografske jedinice broj: 14376
Termodinamic rearrangement of the pentacyclo[5.4.0.0(2, 6).0)3, 10).0(5, 9)] undecane skeleton
Termodinamic rearrangement of the pentacyclo[5.4.0.0(2, 6).0)3, 10).0(5, 9)] undecane skeleton // Tetrahedron, 54 (1998), 38; 11381-11386 (međunarodna recenzija, članak, znanstveni)
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Naslov
Termodinamic rearrangement of the pentacyclo[5.4.0.0(2, 6).0)3, 10).0(5, 9)] undecane skeleton
Autori
Mlinarić-Majerski, Kata ; Veljković, Jelena ; Marchand, Alan P. ; Ganguly, Bishwajit
Izvornik
Tetrahedron (0040-4020) 54
(1998), 38;
11381-11386
Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni
Ključne riječi
Termodinamic rearrangement; pentacyclo[5.4.0.0(2; 6).0(3; 10).0(5; 9)] undecane
Sažetak
Reaction of pentacyclo[5.4.0.02, 6.03, 10.05, 9]undecane-8, 11-dione (1) with ethanedithiol, when performed in the presence of a Lewis acid catalyst (F3B-OEt2), afforded the corresponding mono(ethylene dithioacetal), 2, along with 7, 8-[(thioethano)thio]pentacyclo[6.3.0.02, 6.03, 10.05, 9]undecan-11-one mono(ethylene dithioacetal) (3). Raney nickel reduction of 2 resulted in hydrogenolysis of both the dithioacetal moiety and the cyclobutane ring in 2 and led to the formation of a 7, 8-[(thioethano)thio]pentacyclo[6.3.0.02, 6.03, 10.05, 9]undecane (11) in 35% yield.
Izvorni jezik
Engleski
Znanstvena područja
Kemija
Citiraj ovu publikaciju:
Časopis indeksira:
- Current Contents Connect (CCC)
- Web of Science Core Collection (WoSCC)
- Science Citation Index Expanded (SCI-EXP)
- SCI-EXP, SSCI i/ili A&HCI
- Scopus
