Pregled bibliografske jedinice broj: 1260292
Characterization and isolation of an 18-crown-6 complex of potassium hydroxide prepared by milling: application to mechanochemical organic synthesis
Characterization and isolation of an 18-crown-6 complex of potassium hydroxide prepared by milling: application to mechanochemical organic synthesis // New journal of chemistry, 47 (2023), 7466-7469 doi:10.1039/D3NJ00364G (međunarodna recenzija, članak, znanstveni)
CROSBI ID: 1260292 Za ispravke kontaktirajte CROSBI podršku putem web obrasca
Naslov
Characterization and isolation of an 18-crown-6 complex of potassium hydroxide prepared by milling: application to mechanochemical organic synthesis
Autori
Vugrin, Leonarda ; Halasz, Ivan ; Geneste, Hervé
Izvornik
New journal of chemistry (1144-0546) 47
(2023);
7466-7469
Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni
Ključne riječi
supramolecular complexation ; mechanochemistry ; potassium encapsulation ; ball milling ; crown ether
Sažetak
The enhanced mechanochemical reactivity of potassium hydroxide (KOH) in the presence of 18-crown-6 ether is supported by potassium complexation under milling and has been demonstrated in the Henry reaction and SNAr hydroxylation: in both cases, the desired product is formed within 10 minutes, but requires the presence of the crown ether.
Izvorni jezik
Engleski
Znanstvena područja
Kemija
POVEZANOST RADA
Projekti:
HRZZ-IP-2020-02-1419 - Sistematika mehanizama u bezotopinskoj ili tekućinski kataliziranoj sintezi u čvrstom stanju (SystForSynt) (Halasz, Ivan, HRZZ ) ( CroRIS)
Ustanove:
Institut "Ruđer Bošković", Zagreb
Citiraj ovu publikaciju:
Časopis indeksira:
- Current Contents Connect (CCC)
- Web of Science Core Collection (WoSCC)
- Science Citation Index Expanded (SCI-EXP)
- SCI-EXP, SSCI i/ili A&HCI
- Scopus
