Leached Copper Correlation with Dissolved Organic Carbon in Sloped Vineyard Soil

Filipović, Lana; Defterdarović, Jasmina; Chen, Rui; Krevh, Vedran; Gerke, Horst H.; Baumgartl, Thomas; Kovač, Zoran; Ondrašek, Gabrijel; Ružičić, Stanko; He, Hailong; Dusek, Jaromir; Filipović, Vilim

doi:10.3390/w15040800

Pregled bibliografske jedinice broj: 1255030

Leached Copper Correlation with Dissolved Organic Carbon in Sloped Vineyard Soil

Filipović, Lana; Defterdarović, Jasmina; Chen, Rui; Krevh, Vedran; Gerke, Horst H.; Baumgartl, Thomas; Kovač, Zoran; Ondrašek, Gabrijel; Ružičić, Stanko; He, Hailong et al.

Leached Copper Correlation with Dissolved Organic Carbon in Sloped Vineyard Soil // Water, 15 (2023), 4; 800, 13 doi:10.3390/w15040800 (međunarodna recenzija, članak, znanstveni)

CROSBI ID: 1255030 Za ispravke kontaktirajte CROSBI podršku putem web obrasca

Naslov
Leached Copper Correlation with Dissolved Organic Carbon in Sloped Vineyard Soil

Autori
Filipović, Lana ; Defterdarović, Jasmina ; Chen, Rui ; Krevh, Vedran ; Gerke, Horst H. ; Baumgartl, Thomas ; Kovač, Zoran ; Ondrašek, Gabrijel ; Ružičić, Stanko ; He, Hailong ; Dusek, Jaromir ; Filipović, Vilim

Izvornik
Water (2073-4441) 15 (2023), 4; 800, 13

Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni

Ključne riječi
trace metal mobility in soil ; hillslope landscape ; soil organic carbon ; copper oxychloride ; vineyard management

Sažetak
The solubility and mobility of copper (Cu) in soil is strongly influenced by the presence of dissolved organic carbon (DOC) ; however, the interactions between Cu and DOC are complex and not yet fully understood. In this study, Cu and DOC concentrations were measured monthly for two years in leachates from self-constructed lysimeters installed at inter- and intra-row vineyard hilltop, backslope, and footslope areas at the SUPREHILL Critical Zone Observatory, Croatia. The aim was to quantify Cu and DOC leaching from the hilltop towards the backslope and the footslope. The assumed strong relationship between Cu and DOC in the leachates was statistically analyzed and explained using chemical equilibrium software. Leachates were analyzed for pH, EC, DOC, Cu, and major ion concentrations. The highest Cu concentrations found in leachates from the intra-row footslope suggested Cu downhill transport. Although not strong, a significant positive correlation between Cu and DOC in footslope leachates confirmed the relevance of Cu complexation by DOC. Speciation confirmed that more than 99.9% of total Cu in leachates was found as a Cu-DOC complex. Data implied the role of soil water flow pathways in explaining Cu downhill transport. Critical timing for applying Cu fungicides at sloped vineyards was highlighted.

Izvorni jezik
Engleski

Znanstvena područja
Rudarstvo, nafta i geološko inženjerstvo, Poljoprivreda (agronomija), Interdisciplinarne biotehničke znanosti

POVEZANOST RADA

Projekti:
--UIP-2019-04-5409 - Podpovršinski preferencijalni transportni procesi u poljoprivrednim padinskim tlima (SUPREHILL) (Filipović, Vilim) ( CroRIS)

Ustanove:
Agronomski fakultet, Zagreb,
Rudarsko-geološko-naftni fakultet, Zagreb

Profili:

Stanko Ružičić (autor)