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Pregled bibliografske jedinice broj: 1232824

Controllable synthesis and transformations of magnetic porphyrin-based zirconium MOFs and MOF composites by mechanochemistry


Karadeniz, Bahar; Vujević, Lucija; Žilić, Dijana; Kveder, Marina; Užarević, Krunoslav
Controllable synthesis and transformations of magnetic porphyrin-based zirconium MOFs and MOF composites by mechanochemistry // 10th International Conference on Mechanochemistry and Mechanical Alloying - Book of Abstracts / Delogu, Francesco ; Colacino, Evelina (ur.).
Cagliari: Universita degli Studi di Cagliari, 2022. str. 56-56 (predavanje, međunarodna recenzija, sažetak, znanstveni)


CROSBI ID: 1232824 Za ispravke kontaktirajte CROSBI podršku putem web obrasca

Naslov
Controllable synthesis and transformations of magnetic porphyrin-based zirconium MOFs and MOF composites by mechanochemistry

Autori
Karadeniz, Bahar ; Vujević, Lucija ; Žilić, Dijana ; Kveder, Marina ; Užarević, Krunoslav

Vrsta, podvrsta i kategorija rada
Sažeci sa skupova, sažetak, znanstveni

Izvornik
10th International Conference on Mechanochemistry and Mechanical Alloying - Book of Abstracts / Delogu, Francesco ; Colacino, Evelina - Cagliari : Universita degli Studi di Cagliari, 2022, 56-56

Skup
10th International Conference on Mechanochemistry and Mechanical Alloying (INCOME2022)

Mjesto i datum
Cagliari, Italija, 06.06.2022. - 10.06.2022

Vrsta sudjelovanja
Predavanje

Vrsta recenzije
Međunarodna recenzija

Ključne riječi
MOFs, Mechanochemistry, EPR

Sažetak
Metal-organic frameworks are porous crystalline materials built from metal nodes bridged by organic linkers. Porphyrins, a group of heterocyclic macromolecules with a large π-aromatic system, are particularly attractive linkers for MOF formation. Various metals can be coordinated to the center of porphyrin to create single-cation metalloporphyrins with advanced electrochemical and photophysical properties. Including porphyrins as building units of MOFs widens the potential application area of both the MOFs and porphyrins. Herein we present the liquid-assisted mechanochemical synthesis of various metalloporphyrin-based metal-organic frameworks. In-situ synchrotron PXRD monitoring has been carried out to demonstrate kinetic and mechanistic details of milling reactions. That data was used to tune the reaction conditions toward the target topologies.1 Continuous-wave and pulsed electron paramagnetic resonance spectroscopy (EPR) at X-band were applied in order to analyze the potential of metalloporphyrin-based MOFs as electron spin qubit candidates. Additionally, we will present here the encapsulation of fullerene C60 into the copper porphyrin MOFs by one-pot mechanochemical reactions, and its effect on the magnetic properties of metalloporphyrin zirconium MOF, C60@Cu0.1PCN223.

Izvorni jezik
Engleski

Znanstvena područja
Kemija



POVEZANOST RADA


Projekti:
HRZZ-PZS-2019-02-4129 - Mehanokemijske i bezotopinske strategije za sintezu funkcionalnih poroznih materijala s naprednim fizičko-kemijskim i katalitičkim svojstvima (MECHADVANCE) (Užarević, Krunoslav, HRZZ - 2019-02) ( CroRIS)
HRZZ-IP-2018-01-3168 - Studija važnosti spinskih međudjelovanja kao osnova za nove pristupe u istraživanju materijala (SPES) (Ilakovac-Kveder, Marina, HRZZ - 2018-01) ( CroRIS)
HRZZ-UIP-2014-09-4744 - Mehanokemijska reaktivnost pod kontroliranim uvjetima temperature i atmosfere za čišću sintezu funkcionalnih materijala (MECHANOCONTROL) (Užarević, Krunoslav, HRZZ - 2014-09) ( CroRIS)
MZO-MZO-DAAD-910-08/18-01/00324 - Magneto-strukturne korelacije u molekulskim magnetskim kompleksima istraživane spektroskopijom elektronske spinske rezonancije (Žilić, Dijana, MZO ) ( CroRIS)

Ustanove:
Institut "Ruđer Bošković", Zagreb


Citiraj ovu publikaciju:

Karadeniz, Bahar; Vujević, Lucija; Žilić, Dijana; Kveder, Marina; Užarević, Krunoslav
Controllable synthesis and transformations of magnetic porphyrin-based zirconium MOFs and MOF composites by mechanochemistry // 10th International Conference on Mechanochemistry and Mechanical Alloying - Book of Abstracts / Delogu, Francesco ; Colacino, Evelina (ur.).
Cagliari: Universita degli Studi di Cagliari, 2022. str. 56-56 (predavanje, međunarodna recenzija, sažetak, znanstveni)
Karadeniz, B., Vujević, L., Žilić, D., Kveder, M. & Užarević, K. (2022) Controllable synthesis and transformations of magnetic porphyrin-based zirconium MOFs and MOF composites by mechanochemistry. U: Delogu, F. & Colacino, E. (ur.)10th International Conference on Mechanochemistry and Mechanical Alloying - Book of Abstracts.
@article{article, author = {Karadeniz, Bahar and Vujevi\'{c}, Lucija and \v{Z}ili\'{c}, Dijana and Kveder, Marina and U\v{z}arevi\'{c}, Krunoslav}, year = {2022}, pages = {56-56}, keywords = {MOFs, Mechanochemistry, EPR}, title = {Controllable synthesis and transformations of magnetic porphyrin-based zirconium MOFs and MOF composites by mechanochemistry}, keyword = {MOFs, Mechanochemistry, EPR}, publisher = {Universita degli Studi di Cagliari}, publisherplace = {Cagliari, Italija} }
@article{article, author = {Karadeniz, Bahar and Vujevi\'{c}, Lucija and \v{Z}ili\'{c}, Dijana and Kveder, Marina and U\v{z}arevi\'{c}, Krunoslav}, year = {2022}, pages = {56-56}, keywords = {MOFs, Mechanochemistry, EPR}, title = {Controllable synthesis and transformations of magnetic porphyrin-based zirconium MOFs and MOF composites by mechanochemistry}, keyword = {MOFs, Mechanochemistry, EPR}, publisher = {Universita degli Studi di Cagliari}, publisherplace = {Cagliari, Italija} }




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