Pregled bibliografske jedinice broj: 1225009
Complementarity of solution and solid state mechanochemical reaction conditions demonstrated by 1,2-debromination of tricyclic imides
Complementarity of solution and solid state mechanochemical reaction conditions demonstrated by 1,2-debromination of tricyclic imides // 25th Annual Green Chemistry & Engineering Conference
online, 2021. (poster, međunarodna recenzija, neobjavljeni rad, znanstveni)
CROSBI ID: 1225009 Za ispravke kontaktirajte CROSBI podršku putem web obrasca
Naslov
Complementarity of solution and solid state mechanochemical reaction conditions demonstrated by 1,2-debromination of tricyclic imides
Autori
Štrbac, Petar ; Margetić, Davor
Vrsta, podvrsta i kategorija rada
Sažeci sa skupova, neobjavljeni rad, znanstveni
Skup
25th Annual Green Chemistry & Engineering Conference
Mjesto i datum
Online, 14.06.2021. - 18.06.2021
Vrsta sudjelovanja
Poster
Vrsta recenzije
Međunarodna recenzija
Ključne riječi
debromination ; mechanochemistry ; Diels-Alder
Sažetak
Solution phase 1, 2-debromination of polycyclic imide using Zn/Ag couple was successfully transferred to solid state mechanochemical conditions. The Zn/Ag couple was replaced by Zn/Cu couple which was prepared without any metal activation by in situ ball milling of zinc and copper dusts. The advantage of ball milling process is that whole procedure is operationally very simplified. Alkene generated was trapped in situ by several dienes and the respective Diels-Alder cycloadducts were obtained. It was demonstrated that mechanochemical conditions offer complementary conditions to solution (thermal) reaction conditions by allowing reactions to proceed which were not possible in solution and vice versa.
Izvorni jezik
Engleski
Znanstvena područja
Kemija
POVEZANOST RADA
Projekti:
HRZZ-IP-2018-01-3298 - Cikloadicijske strategije prema policikličkim gvanidinima (CycloGu) (Margetić, Davor, HRZZ - 2018-01) ( CroRIS)
Ustanove:
Institut "Ruđer Bošković", Zagreb
