Pregled bibliografske jedinice broj: 1218298
Complementarity of solution and solid state mechanochemical reaction conditions demonstrated by 1,2-debromination of tricyclic imides
Complementarity of solution and solid state mechanochemical reaction conditions demonstrated by 1,2-debromination of tricyclic imides // Beilstein journal of organic chemistry, 18 (2022), 746-753 doi:10.3762/bjoc.18.75 (međunarodna recenzija, članak, znanstveni)
CROSBI ID: 1218298 Za ispravke kontaktirajte CROSBI podršku putem web obrasca
Naslov
Complementarity of solution and solid state
mechanochemical reaction conditions demonstrated
by 1,2-debromination of tricyclic imides
Autori
Štrbac, Petar ; Margetić, Davor
Izvornik
Beilstein journal of organic chemistry (2195-951X) 18
(2022);
746-753
Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni
Ključne riječi
ball milling ; cycloaddition ; debromination ; Diels−Alder reaction ; mechanochemistry
Sažetak
The solution phase 1, 2-debromination of polycyclic imides using the Zn/Ag couple was successfully transferred to solid state mechanochemical conditions. The Zn/Ag couple was replaced by the Zn/Cu couple which was prepared without any metal activation by in situ ball milling of zinc and copper dusts. The advantage of the ball milling process is that the whole procedure is operationally very simplified. The reactive alkene generated was trapped in situ by several dienes and the respective Diels−Alder cycloadducts were obtained. It was demonstrated that mechanochemical milling offers complementary conditions to solution (thermal) reaction by allowing chemical transformations to proceed which were not possible in solution and vice versa.
Izvorni jezik
Engleski
Znanstvena područja
Kemija
POVEZANOST RADA
Projekti:
HRZZ-IP-2018-01-3298 - Cikloadicijske strategije prema policikličkim gvanidinima (CycloGu) (Margetić, Davor, HRZZ - 2018-01) ( CroRIS)
Ustanove:
Institut "Ruđer Bošković", Zagreb
Citiraj ovu publikaciju:
Časopis indeksira:
- Current Contents Connect (CCC)
- Web of Science Core Collection (WoSCC)
- Science Citation Index Expanded (SCI-EXP)
- SCI-EXP, SSCI i/ili A&HCI
- Scopus
