Pregled bibliografske jedinice broj: 1216251
Consecutive Utilization of Mechanochemical and Microwave Methods for the Synthesis of Boc-2- amino-quinazolin-4(3H)-ones and DFT Study of Mechanism 6π-Diazaelectrocyclization Process
Consecutive Utilization of Mechanochemical and Microwave Methods for the Synthesis of Boc-2- amino-quinazolin-4(3H)-ones and DFT Study of Mechanism 6π-Diazaelectrocyclization Process // ChemistrySelect, 7 (2022), 13; e202200633, 12 doi:10.1002/slct.202200633 (međunarodna recenzija, članak, znanstveni)
CROSBI ID: 1216251 Za ispravke kontaktirajte CROSBI podršku putem web obrasca
Naslov
Consecutive Utilization of Mechanochemical and
Microwave Methods for the Synthesis of Boc-2-
amino-quinazolin-4(3H)-ones and DFT Study of
Mechanism 6π-Diazaelectrocyclization Process
Autori
Antol, Ivana ; Glasovac, Zoran ; Murata, Yasujiro ; Hashikawa, Yoshifumi ; Margetić, Davor
Izvornik
ChemistrySelect (2365-6549) 7
(2022), 13;
E202200633, 12
Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni
Ključne riječi
Guanylation ; electrocyclization ; DFT
Sažetak
Sustainable organic synthesis Guanylation of aromatic amines and thermal electrocyclization could be carried out by consecutive employment of sustainable synthetic methods - mechanosynthesis and microwave irradiation. Quantum-chemical calculations DFT methods suggest the mechanistic details, with crucial involvement of solvation in the key processes - elimination of Boc substituent and 1, 5 H-shift. Relative reactivities and regioselectivities of series of aromatic guanidines was predicted correctly.
Izvorni jezik
Engleski
Znanstvena područja
Kemija
POVEZANOST RADA
Projekti:
HRZZ-IP-2018-01-3298 - Cikloadicijske strategije prema policikličkim gvanidinima (CycloGu) (Margetić, Davor, HRZZ - 2018-01) ( CroRIS)
Ustanove:
Institut "Ruđer Bošković", Zagreb
Citiraj ovu publikaciju:
Časopis indeksira:
- Current Contents Connect (CCC)
- Web of Science Core Collection (WoSCC)
- Science Citation Index Expanded (SCI-EXP)
- SCI-EXP, SSCI i/ili A&HCI
- Scopus
