Pregled bibliografske jedinice broj: 1211118
Piezochromic luminescence of dicoronylene: Key for revealing hidden Raman modes at high pressure
Piezochromic luminescence of dicoronylene: Key for revealing hidden Raman modes at high pressure // Carbon, 197 (2022), 563-569 doi:10.1016/j.carbon.2022.06.009 (međunarodna recenzija, članak, znanstveni)
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Naslov
Piezochromic luminescence of dicoronylene: Key for
revealing hidden Raman modes at high pressure
Autori
Nakagawa, Takeshi ; Dalladay-Simpson, Philip ; Bu, Kejun ; Guo, Songhao ; Vrankić, Martina ; Wang, Dong ; Sereika, Raimundas ; Zhang, Jianbo ; Zhang, Caoshun ; Hu, Qingyang ; Lü, Xujie ; Ding, Yang ; Mao, Ho-kwang
Izvornik
Carbon (0008-6223) 197
(2022);
563-569
Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni
Ključne riječi
Polycyclic aromatic hydrocarbons ; Fluorescence ; Piezochromism ; Raman spectroscopy ; High pressure
Sažetak
Molecular crystals of dicoronylene (C48H20), a member of very large polycyclic aromatic hydrocarbons (PAHs), exhibits strong red fluorescence under ambient conditions. This strong fluorescence induced by visible light excitation obscures entire Raman spectrum of dicoronylene. We employed in-situ high-pressure photoluminescence spectroscopy to observe a reversible piezochromic effect, in which the fluorescence exhibits a drastic red-shift with a rapid quenching of intensity. Above 4 GPa, under red-shifted and reduced fluorescence, hidden Raman modes are observed with 532 nm green laser up to 20 GPa. In this work, we show that the application of pressure can finely tune the fluorescence of dicoronylene, allowing the observation of the Raman spectrum with an appropriate laser wavelength and we discovered that dicoronylene has high chemical stability among PAH molecules with multiple aromatic rings.
Izvorni jezik
Engleski
Znanstvena područja
Fizika, Kemija
Citiraj ovu publikaciju:
Časopis indeksira:
- Current Contents Connect (CCC)
- Web of Science Core Collection (WoSCC)
- Science Citation Index Expanded (SCI-EXP)
- SCI-EXP, SSCI i/ili A&HCI
- Scopus