Naslov
Photochemical production of KCd excimer bands

Autori
Azinović, Davorka ; Milošević, Slobodan ; Pichler, Goran

Izvornik
Chemical Physics Letters (0009-2614) 233 (1995), 4; 477-482

Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni

Ključne riječi
KCd

Sažetak
The electronically excited KCd 2 ‘fI state has been populated in a photochemical reaction of K&C ‘TI, ) with Cd(5 ‘S, , ). The K-Cd vapor mixture was prepared in a crossed heat-pipe oven. The atom densities of the K and Cd atoms in the vapor mixture were controlled by preparation of the amalgams with different mole fraction ratios of the relevant components. A new diffuse excimer band was observed in the region from 600 to 660 nm. Quantum mechanical spectral simulations for the KCd 2 ‘fI + X 2ZZ+ transition were performed, using potential energy curves calculated by Czuchaj, Rebentrost, Stoll and Preuss and showed good agreement with experiment. Other KCd transitions observed in different experiments are discussed.

Izvorni jezik
Engleski

Znanstvena područja
Fizika

POVEZANOST RADA