Pregled bibliografske jedinice broj: 1199700
Synthesis of ligated-metal species by laser vaporization electrospray ionization (LAVESI)
Synthesis of ligated-metal species by laser vaporization electrospray ionization (LAVESI) // International Journal of Mass Spectrometry, 387 (2015), 45-50 doi:10.1016/j.ijms.2015.07.005 (međunarodna recenzija, članak, znanstveni)
CROSBI ID: 1199700 Za ispravke kontaktirajte CROSBI podršku putem web obrasca
Naslov
Synthesis of ligated-metal species by laser
vaporization electrospray ionization (LAVESI)
Autori
Vojkovic, Marin ; Rayane, Driss ; Bertorelle, Franck ; Antoine, Rodolphe ; Broyer, Michel ; Dugourd, Philippe
Izvornik
International Journal of Mass Spectrometry (1387-3806) 387
(2015);
45-50
Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni
Ključne riječi
hybrid metal species ; laser vaporisation ; ESI ; silver ; gold ; copper ; ligated metal complex
Sažetak
We describe a new method for the production of hybrid metal species based on laser vaporization electrospray ionization (LAVESI) mass spectrometry. It consists of an ambient pressure laser vaporization of a metal rod located in the spray of an ESI source. Metal species generated by vaporization of the rod react with molecular ligands present in the spray to form ligated metal species, which are analyzed using a linear quadrupole ion trap. First results obtained by vaporizing silver, gold and copper rods and electrospraying a thioglycolic acid solution are reported. This leads to the formation of ligated metal species, which are transferred to the linear ion trap and mass analyzed. Their composition and size are discussed and compared to the ones obtained from electrospraying a metal salt solution.
Izvorni jezik
Engleski
Znanstvena područja
Fizika, Kemija, Interdisciplinarne prirodne znanosti
Citiraj ovu publikaciju:
Časopis indeksira:
- Current Contents Connect (CCC)
- Web of Science Core Collection (WoSCC)
- Science Citation Index Expanded (SCI-EXP)
- SCI-EXP, SSCI i/ili A&HCI
- Scopus
