Recent advances in the synthesis of five-membered cyclic carbonates and carbamates from allylic or propargylic substrates and CO2

Vranješević, Filip; Kolympadi Markovic, Maria; Matulja, Dario; Ambrožić, Gabriela; Sordo, José Ángel; Laclef, Sylvain; Vrček, Valerije; Marković, Dean

doi:10.3390/catal12050547

Pregled bibliografske jedinice broj: 1195393

Recent advances in the synthesis of five- membered cyclic carbonates and carbamates from allylic or propargylic substrates and CO2

Vranješević, Filip; Kolympadi Markovic, Maria; Matulja, Dario; Ambrožić, Gabriela; Sordo, José Ángel; Laclef, Sylvain; Vrček, Valerije; Marković, Dean

Recent advances in the synthesis of five- membered cyclic carbonates and carbamates from allylic or propargylic substrates and CO2 // Catalysts, 12 (2022), 5; 547-573 doi:10.3390/catal12050547 (međunarodna recenzija, članak, znanstveni)

CROSBI ID: 1195393 Za ispravke kontaktirajte CROSBI podršku putem web obrasca

Naslov
Recent advances in the synthesis of five- membered cyclic carbonates and carbamates from allylic or propargylic substrates and CO2

Autori
Vranješević, Filip ; Kolympadi Markovic, Maria ; Matulja, Dario ; Ambrožić, Gabriela ; Sordo, José Ángel ; Laclef, Sylvain ; Vrček, Valerije ; Marković, Dean

Izvornik
Catalysts (2073-4344) 12 (2022), 5; 547-573

Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni

Ključne riječi
carbamates ; carbonates ; carbon dioxide ; mechanisms ; metal-catalyzed ; organocatalyzed

Sažetak
The organic carbamates and carbonates are highly desirable compounds that have found a wide range of applications in drug design, medicinal chemistry, material science, and the polymer industry. The development of new catalytic carbonate and carbamate forming reactions, which employ carbon dioxide as a cheap, green, abundant, and easily available reagent, would thus represent an ideal substitution for existing methods. In this review, the advancements in the catalytic conversion of allylic and propargylic alcohols and amines to corresponding five- membered cyclic carbonates and carbamates are summarized. Both the metal- and the organocatalyzed methods are reviewed, as well as the proposed mechanisms and key intermediates of the illustrated carbonate and carbamate forming reactions.

Izvorni jezik
Engleski

Znanstvena područja
Kemija

POVEZANOST RADA

Projekti:
IP-2019-04-8846 - In-silico potpomognut dizajn supstrata za hvatanje CO2 u katalitičkoj formaciji karbonata i karbamata (INDICATIOR) (Marković, Dean, HRZZ - 2019-04) ( CroRIS)
NadSve-Sveučilište u Rijeci-uniri-prirod-18-102 - Razvoj novih nanotehnološki unaprijeđenih materijala otpornih na stvaranje bakterijskih biofilmova (Marković, Dean, NadSve ) ( CroRIS)
EK-KF-KK.01.1.1.01.0002 - Bioprospecting Jadranskog mora (Jerković, Igor; Dragović-Uzelac, Verica; Šantek, Božidar; Čož-Rakovac, Rozelinda; Kraljević Pavelić, Sandra; Jokić, Stela, EK ) ( CroRIS)
EK-EFRR-RC.2.2.06-0001 - Razvoj istraživačke infrastrukture na kampusu Sveučilišta u Rijeci (RISK) (Ožanić, Nevenka, EK - Operativni program Regionalna konkurentnost) ( CroRIS)