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Pregled bibliografske jedinice broj: 1193910

Real-Time Observation of “Soft” Magic-Size Clusters during Hydrolysis of the Model Metallodrug Bismuth Disalicylate

Szczerba, Daniel; Tan, Davin; Do, Jean-Louis; Titi, Hatem M; Mouhtadi, Siham; Chaumont, Denis; de Lucas, María del Carmen Marco; Geoffroy, Nicolas; Meyer, Michel; Rousselin, Yoann et al.
Real-Time Observation of “Soft” Magic-Size Clusters during Hydrolysis of the Model Metallodrug Bismuth Disalicylate // Journal of the American Chemical Society, 143 (2021), 16332-16336 doi:10.1021/jacs.1c07186 (međunarodna recenzija, članak, znanstveni)

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Naslov
Real-Time Observation of “Soft” Magic-Size Clusters during Hydrolysis of the Model Metallodrug Bismuth Disalicylate

Autori
Szczerba, Daniel ; Tan, Davin ; Do, Jean-Louis ; Titi, Hatem M ; Mouhtadi, Siham ; Chaumont, Denis ; de Lucas, María del Carmen Marco ; Geoffroy, Nicolas ; Meyer, Michel ; Rousselin, Yoann ; Hudspeth, Jessica M ; Schwanen, Valérie ; Spoerk-Erdely, Petra ; Dippel, Ann-Christin ; Ivashko, Oleh ; Gutowski, Olof ; Glaevecke, Philipp ; Bazhenov, Vasilii ; Arhangelskis, Mihails ; Halasz, Ivan ; Friščić, Tomislav ; Kimber. Simon AJ

Izvornik
Journal of the American Chemical Society (0002-7863) 143 (2021); 16332-16336

Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni

Ključne riječi
Crystallization ; Group theory ; Bismuth ; Cluster chemistry ; Metal clusters

Sažetak
Colloidal bismuth therapeutics have been used for hundreds of years, yet remain mysterious. Here we report an X-ray pair distribution function (PDF) study of the solvolysis of bismuth disalicylate, a model for the metallodrug bismuth subsalicylate (Pepto-Bismol). This reveals catalysis by traces of water, followed by multistep cluster growth. The ratio of the two major species, {; ; Bi9O7}; ; and {; ; Bi38O44}; ; , depends on exposure to air, time, and the solvent. The solution-phase cluster structures are of significantly higher symmetry in comparison to solid-state analogues, with reduced off-center Bi3+ displacements. This explains why such “magic-size” clusters can be both stable enough to crystallize and sufficiently labile for further growth.

Izvorni jezik
Engleski

Znanstvena područja
Kemija



POVEZANOST RADA

Ustanove:
Institut "Ruđer Bošković", Zagreb

Profili:

Avatar Url Ivan Halasz (autor)

Poveznice na cjeloviti tekst rada:

doi doi.org pubs.acs.org

Citiraj ovu publikaciju:

Szczerba, Daniel; Tan, Davin; Do, Jean-Louis; Titi, Hatem M; Mouhtadi, Siham; Chaumont, Denis; de Lucas, María del Carmen Marco; Geoffroy, Nicolas; Meyer, Michel; Rousselin, Yoann et al.
Real-Time Observation of “Soft” Magic-Size Clusters during Hydrolysis of the Model Metallodrug Bismuth Disalicylate // Journal of the American Chemical Society, 143 (2021), 16332-16336 doi:10.1021/jacs.1c07186 (međunarodna recenzija, članak, znanstveni)
Szczerba, D., Tan, D., Do, J., Titi, H., Mouhtadi, S., Chaumont, D., de Lucas, M., Geoffroy, N., Meyer, M. & Rousselin, Y. (2021) Real-Time Observation of “Soft” Magic-Size Clusters during Hydrolysis of the Model Metallodrug Bismuth Disalicylate. Journal of the American Chemical Society, 143, 16332-16336 doi:10.1021/jacs.1c07186.
@article{article, author = {Szczerba, Daniel and Tan, Davin and Do, Jean-Louis and Titi, Hatem M and Mouhtadi, Siham and Chaumont, Denis and de Lucas, Mari\'a del Carmen Marco and Geoffroy, Nicolas and Meyer, Michel and Rousselin, Yoann and Hudspeth, Jessica M and Schwanen, Val\'{e}rie and Spoerk-Erdely, Petra and Dippel, Ann-Christin and Ivashko, Oleh and Gutowski, Olof and Glaevecke, Philipp and Bazhenov, Vasilii and Arhangelskis, Mihails and Halasz, Ivan and Fris\vc\vic\', Tomislav}, year = {2021}, pages = {16332-16336}, DOI = {10.1021/jacs.1c07186}, keywords = {Crystallization, Group theory, Bismuth, Cluster chemistry, Metal clusters}, journal = {Journal of the American Chemical Society}, doi = {10.1021/jacs.1c07186}, volume = {143}, issn = {0002-7863}, title = {Real-Time Observation of “Soft” Magic-Size Clusters during Hydrolysis of the Model Metallodrug Bismuth Disalicylate}, keyword = {Crystallization, Group theory, Bismuth, Cluster chemistry, Metal clusters} }
@article{article, author = {Szczerba, Daniel and Tan, Davin and Do, Jean-Louis and Titi, Hatem M and Mouhtadi, Siham and Chaumont, Denis and de Lucas, Mari\'a del Carmen Marco and Geoffroy, Nicolas and Meyer, Michel and Rousselin, Yoann and Hudspeth, Jessica M and Schwanen, Val\'{e}rie and Spoerk-Erdely, Petra and Dippel, Ann-Christin and Ivashko, Oleh and Gutowski, Olof and Glaevecke, Philipp and Bazhenov, Vasilii and Arhangelskis, Mihails and Halasz, Ivan and Fris\vc\vic\', Tomislav}, year = {2021}, pages = {16332-16336}, DOI = {10.1021/jacs.1c07186}, keywords = {Crystallization, Group theory, Bismuth, Cluster chemistry, Metal clusters}, journal = {Journal of the American Chemical Society}, doi = {10.1021/jacs.1c07186}, volume = {143}, issn = {0002-7863}, title = {Real-Time Observation of “Soft” Magic-Size Clusters during Hydrolysis of the Model Metallodrug Bismuth Disalicylate}, keyword = {Crystallization, Group theory, Bismuth, Cluster chemistry, Metal clusters} }

Časopis indeksira:


  • Current Contents Connect (CCC)
  • Web of Science Core Collection (WoSCC)
    • Science Citation Index Expanded (SCI-EXP)
    • SCI-EXP, SSCI i/ili A&HCI
  • Scopus
  • MEDLINE
  • Nature Index

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