Naslov
Heteropolynuclear [MnIICrIII] oxalate-bridged coordination compounds with dimethylethylammonium cation – influence of N-donors ligand

Autori
Lozančić, Ana ; Molčanov, Krešimir ; Jurić, Marijana

Vrsta, podvrsta i kategorija rada
Sažeci sa skupova, sažetak, znanstveni

Izvornik
6. simpozij studenata doktorskih studija PMF-a : knjiga sažetaka = 6th Faculty of Science PhD student symposium : book of abstracts / Schneider, Petra - Zagreb : Prirodoslovno-matematički fakultet Sveučilišta u Zagrebu, 2022, 270-271

ISBN
978-953-6076-93-2

Skup
6. Simpozij studenata doktorskih studija PMF-a = 6th Faculty of Science PhD Student Symposium

Mjesto i datum
Zagreb, Hrvatska, 23.04.2022. - 24.04.2022

Vrsta sudjelovanja
Poster

Vrsta recenzije
Domaća recenzija

Ključne riječi
coordination polymers ; oxalate complex ; proton ; conductivity

Sažetak
Proton conductivity has recently been regarded as a new functionality of the metal-organic compounds due to their crystallinity and high porosity as well design ability and tunability in structure and property. The simplest method to introduce proton carriers is to include a counterion such as hydronium (H3O+), ammonium [NH4+, (CH3)2NH2+, ...] or anion (SO42-), resulting in the charged compounds. The counterions form the hydrogen-bonding with the guest water or other constituents of compound, making proton-conducting pathways composed of hydrogen-bond networks. Conductivity can also be achieved by introducing of functionalized structural components such as non-coordinated groups in organic ligands (e.g., -OH, -NH2, -COOH or -SO3H) or by coordinating a metal center with functional molecules as H2O, EtOH, and imidazole.

Izvorni jezik
Engleski

Znanstvena područja
Fizika, Kemija

POVEZANOST RADA