Pregled bibliografske jedinice broj: 1190452
Polyoxomolybdates {;;Mo132};; as supramolecular receptors
Polyoxomolybdates {;;Mo132};; as supramolecular receptors // IV. simpozij supramolekulske kemije – Supramolecular Chemistry 2021
Zagreb, Hrvatska, 2021. str. - (pozvano predavanje, nije recenziran, sažetak, znanstveni)
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Naslov
Polyoxomolybdates {;;Mo132};; as supramolecular
receptors
Autori
Rubčić, Mirta
Vrsta, podvrsta i kategorija rada
Sažeci sa skupova, sažetak, znanstveni
Izvornik
IV. simpozij supramolekulske kemije – Supramolecular Chemistry 2021
/ - , 2021
Skup
IV. simpozij supramolekulske kemije (Supramolecular Chemistry 2021)
Mjesto i datum
Zagreb, Hrvatska, 10.12.2021
Vrsta sudjelovanja
Pozvano predavanje
Vrsta recenzije
Nije recenziran
Ključne riječi
polyoxomolybdates, supramolecular chemistry
Sažetak
Polyoxomolybdates of the {; ; {; ; (MoVI)MoVI5}; ; 12{; ; MoV2}; ; 30 Mo132}; ; type, also known as Keplerates, are anionic clusters of nanometer dimensions. These systems are unique as they can be very easily synthesized and/or derivatized. Due to their specific structure, which includes 20 {; ; Mo9O9}; ; pores through which species of appropriate size can pass, these systems allow the study of various supramolecular phenomena, many of which are of interdisciplinary importance. For example, these anions can act as “nanochromatographs” for different cationic aqua complexes, depending on their size or radius. On the other hand, the relatively simple exchange of coordinated anions, which bind on linker units of the Keplerate cluster, allows fine tuning of their properties such as hydrophilicity/hydrophobicity of their interior wall.
Izvorni jezik
Engleski
Znanstvena područja
Kemija
