Naslov
Can mechanical responses of flexible crystals be controlled and deliberately delivered?

Autori
Đaković, Marijana

Vrsta, podvrsta i kategorija rada
Sažeci sa skupova, sažetak, znanstveni

Izvornik
27th Croatian Meeting of Chemists and Chemical Engineers and 5th Symposium Vladimir Prelog : Book of Abstracts / Marković, Dean ; Meštrović, Ernest ; Namjesnik, Danijel ; Tomašić, Vesna - Zagreb : Hrvatsko kemijsko društvo, 2011, 79-79

Skup
27. hrvatski skup kemičara i kemijskih inženjera (27HSKIKI)

Mjesto i datum
Veli Lošinj, Hrvatska, 05.10.2021. - 08.10.2021

Vrsta sudjelovanja
Predavanje

Vrsta recenzije
Domaća recenzija

Ključne riječi
Crystalline coordination polymers ; cadmium(II) ; mechanical flexibility

Sažetak
The ability of molecular crystals to respond to external stimuli through a variety of mechanical responses has recently started to attract attention of a wider scientific community due to their potential application in emerging technologies. But to be in a position to implement mechanically responsive materials in smart devices a precise control of their responses is needed, and for that purpose a deep understanding of underlying principles leading to a targeted response is a necessity. Despite a growing number of literature reports, the rationale behind the flexible responses has not yet been quite understood. With this in mind, we opted for a systematic approach, and focused on crystalline 1- D coordination polymers as those emerged as ideal model systems for exploring structural prerequisites for delivery of a specific mechanical output due to the preorganization of their molecular subunits. In this contribution, a number of families of 1-D coordination polymers displaying a whole spectrum of mechanical responses will be presented and mechanical outputs rationalized against the key structural features. In addition, several custom-made experiments that allowed a distinction between finely separated mechanical events will be demonstrated and complemented with a number of the state- of-the- art techniques for characterization and quantification of flexible responses.

Izvorni jezik
Engleski

Znanstvena područja
Kemija

POVEZANOST RADA