Pregled bibliografske jedinice broj: 1136318
Inorganic stereochemistry: Geometric isomerism in bis-tridentate ligand complexes
Inorganic stereochemistry: Geometric isomerism in bis-tridentate ligand complexes // Coordination chemistry reviews, 445 (2021), 214051, 21 doi:10.1016/j.ccr.2021.214051 (međunarodna recenzija, pregledni rad, znanstveni)
CROSBI ID: 1136318 Za ispravke kontaktirajte CROSBI podršku putem web obrasca
Naslov
Inorganic stereochemistry: Geometric isomerism in
bis-tridentate ligand complexes
Autori
Pantalon Juraj, Natalija ; Kirin, Srećko I.
Izvornik
Coordination chemistry reviews (0010-8545) 445
(2021);
214051, 21
Vrsta, podvrsta i kategorija rada
Radovi u časopisima, pregledni rad, znanstveni
Ključne riječi
stereochemistry ; isomer ; tridentate ligand ; hexacoordinated complex ; CSD survey
Sažetak
In this review, we analyze the stereochemistry of hexacoordinated metal complexes with flexible tridentate ligands. Unlike rigid ligands, which can adopt only specific coordination modes, flexible ligands open more possibilities to fine-tuning the system for a specific application. Bis-tridentate [M(A-B- A)2] complexes of flexible ligands can form three geometric isomers: mer, trans-fac, and cis-fac. The analysis of crystallographic data for 844 structures found in the Cambridge Structural Database (CSD) elucidates influences on the formation of different isomers, such as steric and electronic properties of the ligand and metal ion, type and substitution of donor atoms, and the possibility of non-covalent interactions.
Izvorni jezik
Engleski
Znanstvena područja
Kemija
POVEZANOST RADA
Projekti:
EK-KK.01.1.1.04.0013 - Inovativna rješenja u katalitičkim proizvodnim procesima za potrebe farmaceutske industrije (CAT PHARMA) (Kirin, Srećko, EK ) ( CroRIS)
IP-2014-09-1461 - Minimalni umjetni enzimi: Proširenje primjene posredne indukcije na nove supstrate i nove asimetrične reakcije (MArtEn) (Kirin, Srećko, HRZZ - 2014-09) ( CroRIS)
Ustanove:
Institut "Ruđer Bošković", Zagreb
Citiraj ovu publikaciju:
Časopis indeksira:
- Current Contents Connect (CCC)
- Web of Science Core Collection (WoSCC)
- Science Citation Index Expanded (SCI-EXP)
- SCI-EXP, SSCI i/ili A&HCI
- Scopus
