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Pregled bibliografske jedinice broj: 1134945

SOMO–HOMO Conversion in Triplet Carbenes

Murata, Ryo; Wang, Zhe; Miyazawa, Yuki; Antol, Ivana; Yamago, Shigeru; Abe, Manabu
SOMO–HOMO Conversion in Triplet Carbenes // Organic letters, 23 (2021), 13; 4955-4959 doi:10.1021/acs.orglett.1c01137 (međunarodna recenzija, članak, znanstveni)

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Naslov
SOMO–HOMO Conversion in Triplet Carbenes

Autori
Murata, Ryo ; Wang, Zhe ; Miyazawa, Yuki ; Antol, Ivana ; Yamago, Shigeru ; Abe, Manabu

Izvornik
Organic letters (1523-7060) 23 (2021), 13; 4955-4959

Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni

Ključne riječi
SOMO-HOMO conversion ; carbenes

Sažetak
In this study, the SOMO–HOMO conversion has been shown for the first time in triplet carbenes embedded in cycloparaphenylene units. The high- lying HOMO originating from the curved π- conjugated system and the low-lying SOMO–1 originating due to the small carbene angle are the key to endowing this interesting electronic configuration. Furthermore, simple planar triplet carbenes such as fluorenylidene were found to possess SOMO–HOMO energy-converted electronic configurations.

Izvorni jezik
Engleski

Znanstvena područja
Kemija



POVEZANOST RADA

Ustanove:
Institut "Ruđer Bošković", Zagreb

Profili:

Avatar Url Ivana Antol (autor)

Poveznice na cjeloviti tekst rada:

doi pubs.acs.org pubs.acs.org doi.org

Citiraj ovu publikaciju:

Murata, Ryo; Wang, Zhe; Miyazawa, Yuki; Antol, Ivana; Yamago, Shigeru; Abe, Manabu
SOMO–HOMO Conversion in Triplet Carbenes // Organic letters, 23 (2021), 13; 4955-4959 doi:10.1021/acs.orglett.1c01137 (međunarodna recenzija, članak, znanstveni)
Murata, R., Wang, Z., Miyazawa, Y., Antol, I., Yamago, S. & Abe, M. (2021) SOMO–HOMO Conversion in Triplet Carbenes. Organic letters, 23 (13), 4955-4959 doi:10.1021/acs.orglett.1c01137.
@article{article, author = {Murata, Ryo and Wang, Zhe and Miyazawa, Yuki and Antol, Ivana and Yamago, Shigeru and Abe, Manabu}, year = {2021}, pages = {4955-4959}, DOI = {10.1021/acs.orglett.1c01137}, keywords = {SOMO-HOMO conversion, carbenes}, journal = {Organic letters}, doi = {10.1021/acs.orglett.1c01137}, volume = {23}, number = {13}, issn = {1523-7060}, title = {SOMO–HOMO Conversion in Triplet Carbenes}, keyword = {SOMO-HOMO conversion, carbenes} }
@article{article, author = {Murata, Ryo and Wang, Zhe and Miyazawa, Yuki and Antol, Ivana and Yamago, Shigeru and Abe, Manabu}, year = {2021}, pages = {4955-4959}, DOI = {10.1021/acs.orglett.1c01137}, keywords = {SOMO-HOMO conversion, carbenes}, journal = {Organic letters}, doi = {10.1021/acs.orglett.1c01137}, volume = {23}, number = {13}, issn = {1523-7060}, title = {SOMO–HOMO Conversion in Triplet Carbenes}, keyword = {SOMO-HOMO conversion, carbenes} }

Časopis indeksira:


  • Current Contents Connect (CCC)
  • Web of Science Core Collection (WoSCC)
    • Science Citation Index Expanded (SCI-EXP)
    • SCI-EXP, SSCI i/ili A&HCI
  • Scopus
  • MEDLINE
  • Nature Index

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