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Pregled bibliografske jedinice broj: 1131589

Phenyl argentate aggregates [AgnPhn+1]− (n = 2–8): Models for the self-assembly of atom-precise polynuclear organometallics

Daly, Steven; Weske, Sebastian; Mravak, Antonija; Krstić, Marjan; Kulesza, Alexander; Antoine, Rodolphe; Bonačić-Koutecký, Vlasta; Dugourd, Philippe; Koszinowski, Konrad; O’Hair, Richard A. J.
Phenyl argentate aggregates [AgnPhn+1]− (n = 2–8): Models for the self-assembly of atom-precise polynuclear organometallics // The Journal of chemical physics, 154 (2021), 22; 224301, 8 doi:10.1063/5.0052697 (međunarodna recenzija, članak, znanstveni)

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Naslov
Phenyl argentate aggregates [AgnPhn+1]− (n = 2–8): Models for the self-assembly of atom-precise polynuclear organometallics

Autori
Daly, Steven ; Weske, Sebastian ; Mravak, Antonija ; Krstić, Marjan ; Kulesza, Alexander ; Antoine, Rodolphe ; Bonačić-Koutecký, Vlasta ; Dugourd, Philippe ; Koszinowski, Konrad ; O’Hair, Richard A. J.

Izvornik
The Journal of chemical physics (0021-9606) 154 (2021), 22; 224301, 8

Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni

Ključne riječi
Electrospray ionization ; UVPD ; organometallic oligomers ; DFT

Sažetak
Electrospray ionization of phenyl argentates formed by transmetalation reactions between phenyl lithium and silver cyanide provides access to the argentate aggregates, [AgnPhn+1]−, which were individually mass-selected for n = 2–8 in order to generate their gas-phase Ultraviolet Photodissociation (UVPD) “action” spectra over the range 304–399 nm. A strong bathochromic shift in optical spectra was observed with increasing size/n. Theoretical calculations allowed the assignment of the experimental UVPD spectra to specific isomer(s) and provided crucial insights into the transition from the 2D to 3D structure of the metallic component with the increasing size of the complex. The [AgnPhn+1]− aggregates contain neither pronounced metallic cluster properties nor ligated metallic cluster features and are thus not superatom complexes. They therefore represent novel organometallic characteristics built from Ag2Ph subunits.

Izvorni jezik
Engleski

Znanstvena područja
Fizika, Kemija, Interdisciplinarne prirodne znanosti



POVEZANOST RADA

Projekti:
EK-KF-KK.01.1.1.01.0003 - STIM-REI (STIM-REI) (Bonačić-Koutecky, Vlasta; Smital, Tvrtko; Orlić, Sandi, EK - KK.01.1.1.01) ( CroRIS)

Ustanove:
Prirodoslovno-matematički fakultet, Split,
Sveučilište u Splitu

Profili:

Avatar Url Vlasta Bonačić-Koutecky (autor)

Avatar Url Marjan Krstić (autor)

Avatar Url Antonija Mravak (autor)

Poveznice na cjeloviti tekst rada:

doi aip.scitation.org

Citiraj ovu publikaciju:

Daly, Steven; Weske, Sebastian; Mravak, Antonija; Krstić, Marjan; Kulesza, Alexander; Antoine, Rodolphe; Bonačić-Koutecký, Vlasta; Dugourd, Philippe; Koszinowski, Konrad; O’Hair, Richard A. J.
Phenyl argentate aggregates [AgnPhn+1]− (n = 2–8): Models for the self-assembly of atom-precise polynuclear organometallics // The Journal of chemical physics, 154 (2021), 22; 224301, 8 doi:10.1063/5.0052697 (međunarodna recenzija, članak, znanstveni)
Daly, S., Weske, S., Mravak, A., Krstić, M., Kulesza, A., Antoine, R., Bonačić-Koutecký, V., Dugourd, P., Koszinowski, K. & O’Hair, R. (2021) Phenyl argentate aggregates [AgnPhn+1]− (n = 2–8): Models for the self-assembly of atom-precise polynuclear organometallics. The Journal of chemical physics, 154 (22), 224301, 8 doi:10.1063/5.0052697.
@article{article, author = {Daly, Steven and Weske, Sebastian and Mravak, Antonija and Krsti\'{c}, Marjan and Kulesza, Alexander and Antoine, Rodolphe and Bona\v{c}i\'{c}-Kouteck\'{y}, Vlasta and Dugourd, Philippe and Koszinowski, Konrad and O’Hair, Richard A. J.}, year = {2021}, pages = {8}, DOI = {10.1063/5.0052697}, chapter = {224301}, keywords = {Electrospray ionization, UVPD, organometallic oligomers, DFT}, journal = {The Journal of chemical physics}, doi = {10.1063/5.0052697}, volume = {154}, number = {22}, issn = {0021-9606}, title = {Phenyl argentate aggregates [AgnPhn+1]− (n = 2–8): Models for the self-assembly of atom-precise polynuclear organometallics}, keyword = {Electrospray ionization, UVPD, organometallic oligomers, DFT}, chapternumber = {224301} }
@article{article, author = {Daly, Steven and Weske, Sebastian and Mravak, Antonija and Krsti\'{c}, Marjan and Kulesza, Alexander and Antoine, Rodolphe and Bona\v{c}i\'{c}-Kouteck\'{y}, Vlasta and Dugourd, Philippe and Koszinowski, Konrad and O’Hair, Richard A. J.}, year = {2021}, pages = {8}, DOI = {10.1063/5.0052697}, chapter = {224301}, keywords = {Electrospray ionization, UVPD, organometallic oligomers, DFT}, journal = {The Journal of chemical physics}, doi = {10.1063/5.0052697}, volume = {154}, number = {22}, issn = {0021-9606}, title = {Phenyl argentate aggregates [AgnPhn+1]− (n = 2–8): Models for the self-assembly of atom-precise polynuclear organometallics}, keyword = {Electrospray ionization, UVPD, organometallic oligomers, DFT}, chapternumber = {224301} }

Časopis indeksira:


  • Current Contents Connect (CCC)
  • Web of Science Core Collection (WoSCC)
    • Science Citation Index Expanded (SCI-EXP)
    • SCI-EXP, SSCI i/ili A&HCI
  • Scopus
  • MEDLINE

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