Pregled bibliografske jedinice broj: 1127698
Effects of the variation of diffusion coefficients in the potentiometric stripping analysis
Effects of the variation of diffusion coefficients in the potentiometric stripping analysis // Electrochemical Science Advances, 1 (2021), 2; e2000013, 8 (međunarodna recenzija, članak, znanstveni)
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Naslov
Effects of the variation of diffusion coefficients
in the potentiometric stripping analysis
Autori
Lovrić, Milivoj
Izvornik
Electrochemical Science Advances (2698-5977) 1
(2021), 2;
E2000013, 8
Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni
Ključne riječi
Potentiometric stripping analysis, diffusion coefficients, signal enhancement, chronopotentiometry, model calculation.
Sažetak
A simple steady state model of potentiometric stripping analysis and its derivative mode that are influenced by the film of adsorbed substance that hinders the diffusion of oxidant and metal ions is developed. The dependence of stripping time and the maximum in the derivative mode on the degree of inhibition is calculated. The responses are enhanced if the flux of oxidant is diminished.
Izvorni jezik
Engleski
Napomena
Dedicated to the memory of dr. Šebojka Komorsky-Lovrić.