Pregled bibliografske jedinice broj: 1124894
Use of a “Shoe-Last” Solid-State Template in the Mechanochemical Synthesis of High-Porosity RHO-Zinc Imidazolate
Use of a “Shoe-Last” Solid-State Template in the Mechanochemical Synthesis of High-Porosity RHO-Zinc Imidazolate // Journal of the American Chemical Society, 140 (2018), 32; 10104-10108 doi:10.1021/jacs.8b05471 (međunarodna recenzija, članak, znanstveni)
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Naslov
Use of a “Shoe-Last” Solid-State Template in the Mechanochemical
Synthesis of High-Porosity RHO-Zinc Imidazolate
Autori
Brekalo, Ivana ; Kane, Christopher M. ; Ley, Amanda N. ; Ramirez, Joseph R. ; Friščić, Tomislav ; Holman, K. Travis
Izvornik
Journal of the American Chemical Society (0002-7863) 140
(2018), 32;
10104-10108
Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni
Ključne riječi
zeolitic imidazolate frameworks ; mechanochemistry ; templation ; porous materials
Sažetak
We report the first use of a nonionic solid (NIS) as a template in mechanosynthesis of a metal–organic framework. Through eight intermolecular C–H···O hydrogen bonds, the macrocyclic MeMeCH2 template predictably functions as a “shoe-last” for the assembly of double-eight rings in the liquid-assisted reaction of ZnO and imidazole (ImH). The resulting new form of ZnIm2 (namely xMeMeCH2@RHO-Zn16Im32) is available in multigram amounts, highly porous, and thermally stable.
Izvorni jezik
Engleski
Znanstvena područja
Kemija
Citiraj ovu publikaciju:
Časopis indeksira:
- Current Contents Connect (CCC)
- Web of Science Core Collection (WoSCC)
- Science Citation Index Expanded (SCI-EXP)
- Arts & Humanities Citation Index (A&HCI)
- SCI-EXP, SSCI i/ili A&HCI
- Scopus
- MEDLINE
- Nature Index
