Pregled bibliografske jedinice broj: 112489
Distribution of three ions in the thin film experiment
Distribution of three ions in the thin film experiment // Book of abstracts / 36th Heyrovsky Discussion ; Electrochemistry of Biological Systems and their Models / Heyrovsky, M. (ur.).
Prag: Jaroslav Heyrovsky Institute, 2003. str. 36-36 (poster, nije recenziran, sažetak, znanstveni)
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Naslov
Distribution of three ions in the thin film experiment
Autori
Lovrić, Milivoj ; Komorsky-Lovrić, Šebojka
Vrsta, podvrsta i kategorija rada
Sažeci sa skupova, sažetak, znanstveni
Izvornik
Book of abstracts / 36th Heyrovsky Discussion ; Electrochemistry of Biological Systems and their Models
/ Heyrovsky, M. - Prag : Jaroslav Heyrovsky Institute, 2003, 36-36
Skup
36 th Heyrovsky Discussion ; Electrochemistry of Biological Systems and their Models
Mjesto i datum
Třešť, Češka Republika, 15.06.2003. - 19.06.2003
Vrsta sudjelovanja
Poster
Vrsta recenzije
Nije recenziran
Ključne riječi
liquid / liquid interface; ionic transfer; migration; diffusion; cyclic voltammetry; decamethylferrocene
Sažetak
In the theoretical model it is assumed that a graphite disk electrode is covered by a thin film of the solution of decamethylferrocene and some supporting electrolyte in nitrobenzene and immersed in an aqueous solution of the same electrolyte. Oxidation of decamethylferrocene is accompanied by the transfer of anions of the electrolyte from water into nitrobenzene. The flux of decamethylferrocenium cations at the electrode surface and the flux of anions at the liquid / liquid interface are separated by the thickness of the film, but the electroneutrality is ensured by the migration of ionic species through the film. Theoretical concentration profiles of ionic species in the film are reported for cyclic voltammetry.
Izvorni jezik
Engleski
Znanstvena područja
Kemija
