Pregled bibliografske jedinice broj: 1120011
Maxima in chronoamperometry of irreversible electrode reactions
Maxima in chronoamperometry of irreversible electrode reactions // Journal of electroanalytical chemistry, 888 (2021), 115187, 7 (međunarodna recenzija, članak, znanstveni)
CROSBI ID: 1120011 Za ispravke kontaktirajte CROSBI podršku putem web obrasca
Naslov
Maxima in chronoamperometry of irreversible electrode reactions
Autori
Lovrić, Milivoj
Izvornik
Journal of electroanalytical chemistry (1572-6657) 888
(2021);
115187, 7
Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni
Ključne riječi
Surface electrode reactions ; Adsorption ; Simulation ; Polarography
Sažetak
A model of irreversible reduction complicated by the reactant adsorption is developed for the constant electrode potential. Chronoamperograms, or dc polarograms consist of two components that flow simultaneously and correspond to the volume and surface electrode reactions. The total response is a wave with the maximum that originates from the dependence of the kinetics of electrode reactions on the surface coverage. The dependence of peak potentials on the reactant concentration is demonstrated and explained. The difference between reversible and irreversible reductions is discussed.
Izvorni jezik
Engleski
Napomena
Dedicated to the memory of Dr. Šebojka Komorsky-Lovrić.
Citiraj ovu publikaciju:
Časopis indeksira:
- Current Contents Connect (CCC)
- Web of Science Core Collection (WoSCC)
- Science Citation Index Expanded (SCI-EXP)
- SCI-EXP, SSCI i/ili A&HCI
- Scopus
