Pregled bibliografske jedinice broj: 1115243
Open versus Interpenetrated: Switchable Supramolecular Trajectories in Mechanosynthesis of a Halogen-Bonded Borromean Network
Open versus Interpenetrated: Switchable Supramolecular Trajectories in Mechanosynthesis of a Halogen-Bonded Borromean Network // Chem, 7 (2021), 1; 146-154 doi:10.1016/j.chempr.2020.10.022 (međunarodna recenzija, članak, znanstveni)
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Naslov
Open versus Interpenetrated: Switchable Supramolecular Trajectories in Mechanosynthesis of a Halogen-Bonded Borromean Network
Autori
Catalano, Luca ; Germann, Luzia S. ; Julien, Patrick A. ; Arhangelskis, Mihails ; Halasz, Ivan ; Užarević, Krunoslav ; Etter, Martin ; Dinnebier, Robert E. ; Ursini, Maurizio ; Cametti, Massimo ; Martí-Rujas, Javier ; Friščić, Tomislav ; Metrangolo, Pierangelo ; Resnati, Giuseppe ; Terraneo, Giancarlo
Izvornik
Chem (2451-9294) 7
(2021), 1;
146-154
Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni
Ključne riječi
halogen bond ; borromean rings ; supramolecular chemistry ; solvent-free synthesis ; mechanochemistry ; polymorph ; crystal engineering ; diiodoperfluoroalkanes ; ball milling ; self-assembly
Sažetak
Precise control over topologically intricate molecular architectures remains an open challenge for chemists due to their inherent structural complexity. We report a simple solvent-free strategy to selectively prepare two multi-component supramolecular crystalline systems based on the halogen bond, endowed with either an unknot topology or a Borromean-type entanglement. Real-time in situ monitoring of the solvent-free mechanochemical synthesis of these three-component halogen-bonded ionic co-crystals reveals that the choice of milling conditions leads to a switch in the supramolecular reaction trajectory, resulting in the selective formation of an open halogen-bonded network or a halogen-bonded Borromean-type assembly.
Izvorni jezik
Engleski
Znanstvena područja
Kemija
POVEZANOST RADA
Ustanove:
Institut "Ruđer Bošković", Zagreb
Citiraj ovu publikaciju:
Časopis indeksira:
- Current Contents Connect (CCC)
- Web of Science Core Collection (WoSCC)
- Science Citation Index Expanded (SCI-EXP)
- SCI-EXP, SSCI i/ili A&HCI
- Scopus