Pregled bibliografske jedinice broj: 1113432
In Situ Monitoring of a Quasi Solid-State Diffusion-Driven Cocrystallization in the Diphenylamine–Benzophenone System
In Situ Monitoring of a Quasi Solid-State Diffusion-Driven Cocrystallization in the Diphenylamine–Benzophenone System // Crystal growth & design, 21 (2021), 3; 1434-1442 doi:10.1021/acs.cgd.0c00991 (međunarodna recenzija, članak, znanstveni)
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Naslov
In Situ Monitoring of a Quasi Solid-State Diffusion-Driven Cocrystallization in the Diphenylamine–Benzophenone System
Autori
Biliškov, Nikola
Izvornik
Crystal growth & design (1528-7483) 21
(2021), 3;
1434-1442
Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni
Ključne riječi
Infrared spectroscopy ; Melting ; Crystallization ; Liquids ; Noncovalent interactions ; Phase diagrams
Sažetak
Diphenylamine reacts with benzophenone in the solid state through the formation of a eutectic liquid intermediate, from which the final product, in the form of a hydrogen-bonded cocrystal, is finally formed. By a simple experiment, the phase diagram of the benzophenone/diphenylamine system is effectively divided into two parts, which enabled monitoring of the overall process from the side of each reactant separately. Accompanied by isothermal and nonisothermal spectroscopic monitoring of the system, this provides additional details of the mechanistic pathway of the process of cocrystal formation through a metastable liquid intermediate phase.
Izvorni jezik
Engleski
Znanstvena područja
Kemija
Citiraj ovu publikaciju:
Časopis indeksira:
- Current Contents Connect (CCC)
- Web of Science Core Collection (WoSCC)
- Science Citation Index Expanded (SCI-EXP)
- SCI-EXP, SSCI i/ili A&HCI
- Scopus
