Naslov
Dispiro[adamantane-2, 2'-1', 3', 6', 9', 11', 14'-hexathiacyclohexadecane-10', 2''- adamantane]

Autori
Višnjevac, Aleksandar ; Kojić-Prodić, Biserka ; Vinković, Marijana ; Mlinarić-Majerski, Kata

Izvornik
Acta Crystallographica C - Crystal Structure Communications (0108-2701) 59 (2003); 314-316

Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni

Ključne riječi
Dispiro[adamantane-2; 2'-1'; 3'; 6'; 9'; 11'; 14'-hexathiacyclohexadecane-10'; 2''- adamantane]

Sažetak
The crystal structure of 2, 10-bis-spiro(2-adamantyliden)-1, 3, 6, 9, 11, 14-hexathiacyclohexadecane, C28 H44 S6, (I) is presented. The conformational features of (I) are compared with the previously reported analogous macrocycles using CSD data. It is shown that the type of the substituent affects considerably the conformation of the macrocycle. A 1H NMR titration of (I) with AgBF4 indicated the formation of the 1:1 complex, that, however, was not crystallised.

Izvorni jezik
Engleski

Znanstvena područja
Kemija

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