Pregled bibliografske jedinice broj: 1090774
The structural, electrical and optical properties of spark plasma sintered BaSn1-Sb O3 ceramics
The structural, electrical and optical properties of spark plasma sintered BaSn1-Sb O3 ceramics // Journal of the European Ceramic Society, 40 (2020), 15; 5566-5575 doi:10.1016/j.jeurceramsoc.2020.06.062 (međunarodna recenzija, članak, znanstveni)
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Naslov
The structural, electrical and optical properties
of spark plasma sintered BaSn1-Sb O3 ceramics
Autori
Vukašinović, Jelena ; Počuča-Nešić, Milica ; Golić, Danijela Luković ; Ribić, Vesna ; Branković, Zorica ; Savić, Slavica M. ; Dapčević, Aleksandra ; Bernik, Slavko ; Podlogar, Matejka ; Kocen, Matej ; Rapljenović, Željko ; Ivek, Tomislav ; Lazović, Vladimir ; Dojčinović, Biljana ; Branković, Goran
Izvornik
Journal of the European Ceramic Society (0955-2219) 40
(2020), 15;
5566-5575
Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni
Ključne riječi
BaSnO3 ; Spark plasma sintering ; Potential barrier ; Low angle grain boundaries ; Electrical conductivity
Sažetak
Antimony doped barium-stannate dense ceramic materials were synthesized using spark plasma sintering technique out of mechanically activated precursor powders. The influence of various Sb concentrations (x = 0.00 – 0.10) on properties of BaSn1-xSbxO3 ceramics was investigated. Relative densities of prepared samples were in the range of (79–96) %. TEM analysis revealed the presence of many dislocations in undoped BaSnO3, and their significant reduction upon doping with Sb. All samples except BaSn0.92Sb0.08O3 exhibit non- linear I-U characteristic, typical for semiconductors with potential barrier at grain boundaries. Low angle grain boundaries found only in BaSn0.92Sb0.08O3 caused the loss of potential barrier at grain boundaries which was confirmed by AC impedance spectroscopy measurements. Consequently, BaSn0.92Sb0.08O3 showed the lowest electrical resistivity and linear I-U characteristic. UV–vis analysis confirmed the increasing of band gap (Burstein–Moss shift) values in all doped samples.
Izvorni jezik
Engleski
Znanstvena područja
Fizika, Kemija
POVEZANOST RADA
Ustanove:
Institut za fiziku, Zagreb
Citiraj ovu publikaciju:
Časopis indeksira:
- Current Contents Connect (CCC)
- Web of Science Core Collection (WoSCC)
- Science Citation Index Expanded (SCI-EXP)
- SCI-EXP, SSCI i/ili A&HCI
- Scopus