Pregled bibliografske jedinice broj: 1089786
Organocatalytic Synthesis of α-Triphenylmethylamines from Diarylketimines and Phenols
Organocatalytic Synthesis of α-Triphenylmethylamines from Diarylketimines and Phenols // Journal of organic chemistry, 85 (2020), 21; 14253-14261 doi:10.1021/acs.joc.0c02225 (međunarodna recenzija, članak, znanstveni)
CROSBI ID: 1089786 Za ispravke kontaktirajte CROSBI podršku putem web obrasca
Naslov
Organocatalytic Synthesis of α-Triphenylmethylamines
from Diarylketimines and Phenols
Autori
Glavač, Danijel ; Topolovčan, Nikola ; Gredičak, Matija
Izvornik
Journal of organic chemistry (0022-3263) 85
(2020), 21;
14253-14261
Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni
Ključne riječi
Hydrocarbons ; Chemical reactions ; Aromatic compounds
Sažetak
A formal Betti reaction between variously substituted phenols and benzophenone-derived imines to afford α-triphenylmethylamines is reported. The key to the success of this transformation is the in situ generation of the reactive benzophenone iminium species under organocatalytic conditions. Different phenols reacted smoothly, enabling the synthesis of an array of α-triphenylmethylamines, which are highly valued structural motifs in bioactive molecules and chemical sensors.
Izvorni jezik
Engleski
Znanstvena područja
Kemija
POVEZANOST RADA
Projekti:
HRZZ-IP-2018-01-4053 - Nove strategije za pripravu tetrasupstituiranih kiralnih centara: asimetrične katalitičke reakcije usmjerene protuanionom (NSYNC-ACDC) (Gredičak, Matija, HRZZ - 2018-01) ( CroRIS)
Ustanove:
Institut "Ruđer Bošković", Zagreb
Citiraj ovu publikaciju:
Časopis indeksira:
- Current Contents Connect (CCC)
- Web of Science Core Collection (WoSCC)
- Science Citation Index Expanded (SCI-EXP)
- SCI-EXP, SSCI i/ili A&HCI
- Scopus
- MEDLINE
