Pregled bibliografske jedinice broj: 1076914
Interactions of zein and zein/rosin nanoparticles with natural polyanion gum arabic
Interactions of zein and zein/rosin nanoparticles with natural polyanion gum arabic // Colloids and surfaces. B, Biointerfaces, 196 (2020), 111289, 7 doi:10.1016/j.colsurfb.2020.111289 (međunarodna recenzija, članak, znanstveni)
CROSBI ID: 1076914 Za ispravke kontaktirajte CROSBI podršku putem web obrasca
Naslov
Interactions of zein and zein/rosin nanoparticles with natural polyanion gum arabic
Autori
Spasojević, Ljiljana ; Bučko, Sandra ; Kovačević, Davor ; Bohinc, Klemen ; Jukić, Jasmina ; Abram, Anže ; Požar, Josip ; Katona, Jaroslav
Izvornik
Colloids and surfaces. B, Biointerfaces (0927-7765) 196
(2020);
111289, 7
Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni
Ključne riječi
Zein ; Rosin ; Nanoparticles ; Interaction ; Gum arabic
Sažetak
The objective of this study was to investigate interactions of zein (Z) and zein/rosin (Z/R) nanoparticles with gum arabic (GA), at different pH. Nanoparticles were firstly prepared by antisolvent precipitation of biopolymers from aqueous ethanol solutions. Nanoparticles suspensions were then dialyzed against water in order to remove ethanol and other impurities, and water suspensions of zein and zein/rosin nanoparticles were obtained. It was shown that composition of nanoparticles affects their surface charge density. Zeta potential of nanoparticles was positive without GA and changed to negative after addition of GA, at all pH tested. SEM analysis proved both Z and Z/R nanoparticles to be spherical and in size around 200 nm. The effect of addition of GA on particle size was determined using dynamic light scattering method. It was found that addition of GA increases size of nanoparticles at pH=4 and pH=5.5, from 150 – 220 nm to 250 – 320 nm. However, at pH=3 it causes aggregation process, and diameter of particles increases up to few micrometres. Isothermal titration calorimetry was used to measure enthalpy changes in reaction between Z or Z/R nanoparticles and GA. Results showed that reaction between GA and Z or Z/R NPs is exothermic at each pH tested, except for Z NPs at pH=3, where it was endothermic. At presented pHs, Z/R NPs were less charged compared to Z NPs, and their surface get saturated with GA molecules more rapidly. Z NPs showed greater enthalpy change in reaction with GA, compared to Z/R NPs.
Izvorni jezik
Engleski
Znanstvena područja
Kemija
POVEZANOST RADA
Ustanove:
Prirodoslovno-matematički fakultet, Zagreb
Citiraj ovu publikaciju:
Časopis indeksira:
- Current Contents Connect (CCC)
- Web of Science Core Collection (WoSCC)
- Science Citation Index Expanded (SCI-EXP)
- SCI-EXP, SSCI i/ili A&HCI
- Scopus
- MEDLINE