Pregled bibliografske jedinice broj: 10724
Free-radical-initiated polymerization of N(p-phenoxy-phenyl)maleimide and copolymerization with styrene, alpha-methylstyrene and beta-methylstyrene
Free-radical-initiated polymerization of N(p-phenoxy-phenyl)maleimide and copolymerization with styrene, alpha-methylstyrene and beta-methylstyrene // Journal of macromolecular science : pure and applied chemistry, A34 (1997), 9; 1619-1628 (međunarodna recenzija, članak, znanstveni)
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Naslov
Free-radical-initiated polymerization of N(p-phenoxy-phenyl)maleimide and copolymerization with styrene, alpha-methylstyrene and beta-methylstyrene
Autori
Vuković, Radivoje ; Fleš, Dragutin ; Erceg, Ana
Izvornik
Journal of macromolecular science : pure and applied chemistry (1060-1325) A34
(1997), 9;
1619-1628
Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni
Ključne riječi
synthesis; CT-complex; phenoxy-phenylmaleimide; copolymerization
Sažetak
Synthesis and free-radical-initiated homopolymerization of phenoxy-phenylmaleimide (PhOPhMI) and copolymerization with styrene (St), (alpha-methylstyrene (alpha-MeSt) and beta-methylstyrene (beta-MeSt) are described. It was found that alternating copolymers are formed under different monomer-to-monomer ratios in the feed and that the mechanism based on the participation of CT-complex best explains the formation of alternating copolymers. Equilibrium constants of CT-complexes are: K(PhOPhMI/St) = 0.20 L/mol; K(PhOPhMI/alpha-MeSt) = 0.05 L/mol ; K(PhOPhMI/beta-MeSt) = 0.02 L/mol. Homopolymer and co-polymers are film-forming materials, stable up to 350 C under TGA conditions. T's and higher transition temperatures are within the thermally stable region.v
Izvorni jezik
Engleski
Znanstvena područja
Kemija
Citiraj ovu publikaciju:
Časopis indeksira:
- Current Contents Connect (CCC)
- Web of Science Core Collection (WoSCC)
- Science Citation Index Expanded (SCI-EXP)
- SCI-EXP, SSCI i/ili A&HCI
- Scopus
