Pregled bibliografske jedinice broj: 1065221
Bis-[3] Ferrocenophanes with Central> E- E’< Bonds (E, E’= P, SiH): Preparation, Properties, and Thermal Activation
Bis-[3] Ferrocenophanes with Central> E- E’< Bonds (E, E’= P, SiH): Preparation, Properties, and Thermal Activation // ChemistryOpen, 8 (2019), 10; 1235-1243 doi:10.1002/open.201900182 (međunarodna recenzija, članak, znanstveni)
CROSBI ID: 1065221 Za ispravke kontaktirajte CROSBI podršku putem web obrasca
Naslov
Bis-[3] Ferrocenophanes with Central> E- E’< Bonds (E, E’= P, SiH): Preparation, Properties, and Thermal Activation
Autori
Isenberg, Stefan ; Weller, Stefan ; Kargin, Denis ; Valić, Srećko ; Schwederski, Brigitte ; Kelemen, Zsolt ; Bruhn, Clemens ; Krekić, Kristijan ; Maurer, Martin ; Feil, Christoph M ; Nieger, Martin ; Gudat, Dietrich ; Nyulászi, László ; Pietschnig, Rudolf
Izvornik
ChemistryOpen (2191-1363) 8
(2019), 10;
1235-1243
Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni
Ključne riječi
ferrocene ; homolytic bond cleavage ; phosphorus ; radicals ; thermolysis
Sažetak
A series of bis-[3]ferrocenophanes of the general type Fe(C5H4E')2E-E(E'C5H4)2Fe (E=P, SiH and E'=PtBu, NneoPentyl, NSi(CH3)3) with an isolobal molecular framework have been prepared and characterized by heteronuclear NMR spectroscopy and X-ray crystallography. The thermal dissociation behavior with respect to homolytic fission of the central bond generating phosphorus centered radicals was investigated using EPR spectroscopy and quantum chemical calculations.
Izvorni jezik
Engleski
Znanstvena područja
Kemija
Napomena
COST Action 1302
POVEZANOST RADA
Projekti:
HRZZ-IP-2018-01-3168 - Studija važnosti spinskih međudjelovanja kao osnova za nove pristupe u istraživanju materijala (SPES) (Ilakovac-Kveder, Marina, HRZZ - 2018-01) ( CroRIS)
Ustanove:
Institut "Ruđer Bošković", Zagreb
Profili:
Srećko Valić
(autor)
Citiraj ovu publikaciju:
Časopis indeksira:
- Current Contents Connect (CCC)
- Web of Science Core Collection (WoSCC)
- Science Citation Index Expanded (SCI-EXP)
- SCI-EXP, SSCI i/ili A&HCI
- Scopus