Naslov
Concentrations and Adsorption Isotherms for Amphiphilic Surfactants in PM1 Aerosols from Different Regions of Europe

Autori
Gerard, Violaine ; Noziere, Barbara ; Fine, Ludovic ; Ferronato, Corinne ; Singh, Dharmendra Kumar ; Frossard, Amanda A. ; Cohen, Ronald C. ; Asmi, Eija ; Lihavainen, Heikki ; Kivekas, Niku ; Aurela, Minna ; Brus, David ; Frka, Sanja ; Cvitešić Kušan, Ana

Izvornik
Environmental science & technology (0013-936X) 53 (2019), 21; 12379-12388

Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni

Ključne riječi
PM1 ; surfactants ; surface tension ; critical micelle concentration ; cloud droplets

Sažetak
Predicting the activation of submicrometer particles into cloud droplets in the atmosphere remains a challenge. The importance of surface tension, σ (mN m−1), in these processes has been evidenced by several works, but information on the "surfactants" lowering σ in actual atmospheric particles remains scarce. In this work, PM1 aerosols from urban, coastal, and remote regions of Europe (Lyon, France, Rogoznica, Croatia, and Pallas, Finland, respectively) were investigated and found to contain amphiphilic surfactants in concentrations up to 2.8 μg m−3 in the air and 1.3 M in the particle dry volume. In Pallas, correlations with the PM1 chemical composition showed that amphiphilic surfactants were present in the entire range of particle sizes, supporting recent works. This implied that they were present in hundreds to thousands of particles cm−3 and not only in a few large particles, as it has been hypothesized. Their adsorption isotherms and critical micelle concentration (CMC) were also determined. The low CMC obtained (3 × 10−5−9 × 10−3 M) implies that surface tension depression should be significant for all the particles containing these compounds, even at activation (growth factor ∼ 10). Amphiphilic surfactants are thus likely to enhance the CCN ability of submicrometer atmospheric particles.

Izvorni jezik
Engleski

Znanstvena područja
Kemija, Interdisciplinarne prirodne znanosti

POVEZANOST RADA