Pregled bibliografske jedinice broj: 1040228
Investigation of the glucosinolates in Hesperis matronalis L. and Hesperis laciniata All.: Unveiling 4′-O-β-D-apiofuranosylglucomatronalin
Investigation of the glucosinolates in Hesperis matronalis L. and Hesperis laciniata All.: Unveiling 4′-O-β-D-apiofuranosylglucomatronalin // Carbohydrate research, 488 (2020) doi:10.1016/j.carres.2019.107898 (međunarodna recenzija, članak, znanstveni)
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Naslov
Investigation of the glucosinolates in Hesperis
matronalis L. and Hesperis laciniata All.:
Unveiling 4′-O-β-D-apiofuranosylglucomatronalin
Autori
Montaut, Sabine ; Read, Sharayah ; Blažević, Ivica ; Nuzillard, Jean-Marc ; Roje, Marin ; Harakat, Dominique ; Rollin, Patrick
Izvornik
Carbohydrate research (0008-6215) 488
(2020);
107898, 0
Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni
Ključne riječi
Hesperis laciniata All. ; Hesperis matronalis L. ; Brassicaceae ; Glucosinolate ; NMR ; LC-MS ; 4′-O-β-D-apiofuranosylglucomatronalin
Sažetak
The glucosinolate (GSL) profiles of wild-growing plants from the genus Hesperis, i.e. Hesperis laciniata All. (leaf, stem, flower, and root) from Croatia and Hesperis matronalis L. (leaf, stem, flower, seed, and root) from Canada, were established by LC-MS. During this investigation, 5-(methylsulfanyl)pentyl- (3), 6- (methylsulfanyl)hexyl- (4), 6- (methylsulfinyl)hexyl- (6), and 4′-α-L- rhamnopyranosyloxybenzyl- (17) GSLs were identified. In addition, the presence of 7- (methylsulfinyl)heptyl GSL (18), hydroxy-(α-L- rhamnopyranosyloxy)benzyl GSL, and of one D- apiosylated analogue of 17 were suggested. Moreover, one new GSL, 4′-O-β-D- apiofuranosylglucomatronalin (19) was isolated from H. laciniata (flower, steam and leaf) and characterized by spectroscopic data interpretation. Finally, we report the presence of 3, 4, 6, 19, glucosinalbin (12), and 4- hydroxyglucobrassicin (20) in H. matronalis and hypothesize the presence of glucomatronalin (13) and 3-hydroxy-6-(methylsulfanyl)hexyl GSL (21).
Izvorni jezik
Engleski
Znanstvena područja
Kemija
POVEZANOST RADA
Projekti:
HRZZ-IP-2016-06-1316 - Biljke kao izvor bioaktivnih sumporovih spojeva te njihova sposobnost hiperakumulacije metala (BioSMe) (Blažević, Ivica, HRZZ - 2016-06) ( CroRIS)
Ustanove:
Kemijsko-tehnološki fakultet, Split,
Institut "Ruđer Bošković", Zagreb
Citiraj ovu publikaciju:
Časopis indeksira:
- Current Contents Connect (CCC)
- Web of Science Core Collection (WoSCC)
- Science Citation Index Expanded (SCI-EXP)
- SCI-EXP, SSCI i/ili A&HCI
- Scopus
- MEDLINE