Pregled bibliografske jedinice broj: 1032695
A structural and infrared study of the charge states of tetrakis (dimethylamino)ethylene
A structural and infrared study of the charge states of tetrakis (dimethylamino)ethylene // The Journal of Chemical Physics, 110 (1999), 7; 3606-3611 doi:10.1063/1.478233 (međunarodna recenzija, članak, znanstveni)
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Naslov
A structural and infrared study of the charge states of tetrakis (dimethylamino)ethylene
(A structural and infrared study of the charge states of tetrakis (dimethylamino)ethylene (TDAE) in TDAE-C60 and (TDAE)(Cl)2)
Autori
Pokhodnia, K. I. ; Papavassiliou, J. ; Umek, P. ; Omerzu, A. ; Mihailovič, D.
Izvornik
The Journal of Chemical Physics (0021-9606) 110
(1999), 7;
3606-3611
Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni
Ključne riječi
MAGNETIC-PROPERTIES ; PHASES ; TETRAKIS(DIMETHYLAMINO)ETHYLENE ; FERROMAGNETISM
Sažetak
The molecular structure and vibrational spectra of the different oxidation states of tetrakis(dimethylamino)ethylene (TDAE) are calculated using structural optimization and normal-mode calculations. The predictions are compared with x-ray structural data and infrared spectra of TDAE, TDAE-C-60 and (TDAE) (Cl)(2). The C-N stretch vibration frequency and axial torsional angle are shown to be sensitive indicators of the charge state of the molecule. TDAE(+), which occurs in TDAE-C-60 is found to have a near-degenerate configurational ground state.
Izvorni jezik
Engleski
Znanstvena područja
Fizika, Interdisciplinarne prirodne znanosti
Citiraj ovu publikaciju:
Časopis indeksira:
- Current Contents Connect (CCC)
- Web of Science Core Collection (WoSCC)
- Science Citation Index Expanded (SCI-EXP)
- SCI-EXP, SSCI i/ili A&HCI
- Scopus
