Pregled bibliografske jedinice broj: 1029737
Iodine uptake and enhanced electrical conductivity in a porous coordination polymer based on cucurbit[6]uril
Iodine uptake and enhanced electrical conductivity in a porous coordination polymer based on cucurbit[6]uril // Inorganic Chemistry Frontiers, 3 (2016), 1393-1397 doi:10.1039/C6QI00305B (međunarodna recenzija, članak, ostalo)
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Naslov
Iodine uptake and enhanced electrical conductivity in a porous coordination polymer based on cucurbit[6]uril
Autori
Lin, Jing-Xiang ; Liang, Jun ; Feng, Ji-Fei ; Karadeniz, Bahar ; Lu, Jian ; Cao, Rong
Izvornik
Inorganic Chemistry Frontiers (2052-1553) 3
(2016);
1393-1397
Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, ostalo
Ključne riječi
Porous Materials ; Coordination Polymer ; Conductivity
Sažetak
A porous coordination polymer [(Na2I2CB[6])·8H2O]n (complex 1 ; CB[6] = cucurbit[6]uril), which absorbs gaseous iodine molecules and forms a polyiodide containing material I2@1, has been prepared and used as an absorbent for iodine uptake. The formation of halogen bonds between discrete iodide ions and iodine molecules has been demonstrated as predominant driving forces for iodine adsorption. Moreover, complex 1 demonstrates enhanced electrical conductivity upon iodine uptake, thanks to the formation of the polyiodide structure. This observation indicates that the discrete iodide matrix in the crystal lattice is an ideal and preferential molecular dock for iodine accommodation.
Izvorni jezik
Engleski
Znanstvena područja
Kemija
Citiraj ovu publikaciju:
Časopis indeksira:
- Current Contents Connect (CCC)
- Web of Science Core Collection (WoSCC)
- Science Citation Index Expanded (SCI-EXP)
- SCI-EXP, SSCI i/ili A&HCI
- Scopus
