Pregled bibliografske jedinice broj: 1024449
Theory of staircase cyclic voltammetry of two electrode reactions coupled by a chemical reaction
Theory of staircase cyclic voltammetry of two electrode reactions coupled by a chemical reaction // Bulgarian chemical communications, 51 (2019), 3; 348-357 (međunarodna recenzija, članak, znanstveni)
CROSBI ID: 1024449 Za ispravke kontaktirajte CROSBI podršku putem web obrasca
Naslov
Theory of staircase cyclic voltammetry of two electrode reactions coupled by a chemical reaction
Autori
Komorsky-Lovrić, Šebojka ; Lovrić, Milivoj
Izvornik
Bulgarian chemical communications (0861-9808) 51
(2019), 3;
348-357
Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni
Ključne riječi
ECE mechanism ; Cyclic voltammetry ; Theory
Sažetak
Two reversible electrode reactions that are connected by either reversible, or totally irreversible chemical reaction are analysed theoretically for staircase cyclic voltammetry. The dependence of peak potentials on the thermodynamic and kinetic parameters is calculated. If the mechanism is permanently in equilibrium, the stability constant of reversible chemical reaction can be determined. Furthermore, the critical kinetic parameter is determined and its application to the measurement of the forward rate constant of chemical reaction is demonstrated. Also, the influence of the kinetics of electrode reactions is discussed.
Izvorni jezik
Engleski
Citiraj ovu publikaciju:
Časopis indeksira:
- Scopus
