Pregled bibliografske jedinice broj: 1016159
Molecules with Twist Bent Bonds. The Synthesis, Properties, and Reactions of trans Bicyclo[4.1.0]hept-3-ene and Certain Methylated Derivatives
Molecules with Twist Bent Bonds. The Synthesis, Properties, and Reactions of trans Bicyclo[4.1.0]hept-3-ene and Certain Methylated Derivatives // Journal of the American Chemical Society, 111 (1989), 7; 2652-2662 doi:10.1021/ja00189a046 (međunarodna recenzija, članak, ostalo)
CROSBI ID: 1016159 Za ispravke kontaktirajte CROSBI podršku putem web obrasca
Naslov
Molecules with Twist Bent Bonds. The Synthesis, Properties, and Reactions of trans Bicyclo[4.1.0]hept-3-ene and Certain Methylated Derivatives
Autori
Gassman, Paul, G. ; Bonser, Steven M. ; Mlinarić-Majerski, Kata
Izvornik
Journal of the American Chemical Society (0002-7863) 111
(1989), 7;
2652-2662
Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, ostalo
Ključne riječi
trans-bicyclo[4.1.0]hept-3-ene ; twist bent bond
Sažetak
Tram-Bicyclc 4.1 .O]h ept-3-ene, 7-methyl-rrum-bicyclo[4..O1 ]hept-3-ene, and 7, 7-dimethyl-~ram-bicyclo[4.O.1]h ept- 1-ene have been synthesize( Comparison of their ease of oxidation with the ease of oxidation of the analogous cis-bicyclo- [4.1 .O]hept-3-enes has been made. Both the thermal and transition-metal complex promoted rearrangements of the trunsbicyclo[4.1 .O]hept-3-enes have been studied. These systems thermally convert to the cis-bicyclo[4.1 .O]hept-3-enes above 100 OC and are catalytically rearranged at ambient temperature. Trans to cis isomerization also occurs at ambient temperature under photo induced single electron transfer conditions.
Izvorni jezik
Engleski
Znanstvena područja
Kemija
Citiraj ovu publikaciju:
Časopis indeksira:
- Current Contents Connect (CCC)
- Web of Science Core Collection (WoSCC)
- Science Citation Index Expanded (SCI-EXP)
- SCI-EXP, SSCI i/ili A&HCI
- Scopus
