Naslov
On the molar volume of multicomponent crystals

Autori
Topić, Edi ; Stilinović, Vladimir

Vrsta, podvrsta i kategorija rada
Sažeci sa skupova, sažetak, znanstveni

Izvornik
Solid state science and research 2019 : book of abstracts / Biliškov, Nikola - Zagreb : Institut Ruđer Bošković, 2019, 113-113

ISBN
978-953-7941-32-1

Skup
Solid State Science and Research Meeting

Mjesto i datum
Zagreb, Hrvatska, 27.06.2019. - 29.06.2019

Vrsta sudjelovanja
Poster

Vrsta recenzije
Međunarodna recenzija

Ključne riječi
molar volume ; multicomponent crystals

Sažetak
Pressure is an important, but often overlooked variable in soft solid-state science. Even though static[1] and shock[2] phase behavior is known for some pure compounds, knowledge about pressure dependence of solid-state reactions is practically non-existent. In this work, theoretical pressure dependence for formation of binary cocrystals from its components is explored, using Cambridge Structural Database[3] as a data source. Interestingly, distribution of reaction molar volume is not quite symmetrical, with more entries having molar volume greater than sum of molar volumes of its components. This suggests that higher pressure would usually work against cocrystallization. Structural correlation, extreme cases and potential of “pressure-only” synthesis are presented.

Izvorni jezik
Engleski

Znanstvena područja
Kemija

POVEZANOST RADA