Naslov
Vapor and thermally induced solid-state structural transformations

Autori
Mandarić, Mirna ; Vrdoljak, Višnja

Vrsta, podvrsta i kategorija rada
Sažeci sa skupova, sažetak, znanstveni

Izvornik
SCIRES 2019: Book of Abstracts / Biliškov, Nikola - Zagreb : Institut Ruđer Bošković, 2019, 91-91

ISBN
978-953-7941-32-1

Skup
Solid State Science and Research Meeting

Mjesto i datum
Zagreb, Hrvatska, 27.06.2019. - 29.06.2019

Vrsta sudjelovanja
Poster

Vrsta recenzije
Međunarodna recenzija

Ključne riječi
molybdenum(VI) complexes ; hydrazone ; vapour and thermally induced structural transformations ; SC-SC transformations

Sažetak
Reactions or structural transformations in the solid-state are more difficult than in solution because they involve new bond formation or breakage with restricted molecular movements. [1] Synthesis of the mononuclear complex was carried out by using bis(pentane-2, 4- dionato)dioxomolybdenum(VI) and 4- methoxysalicylaldehyde isonicotinoyl hydrazine. The mononuclear complex was used as a precursor for structural transformations in the solid state (Figure 1). Crystals of [MoO2(L)(MeOH)] were exposed to organic solvent vapors. Also, thermally-induced transformations were investigated. These reactions resulted in the formation of the coordination polymer [MoO2(L)]n. When [MoO2(L)(MeOH)] was exposed to water vapor the coordinated MeOH ligand were replaced with H2O. These transformations occured in a SC-SC manner.[2]

Izvorni jezik
Engleski

Znanstvena područja
Kemija

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