Pregled bibliografske jedinice broj: 1003528
Reinvestigation of the Branimycin Stereochemistry at Position 17-C
Reinvestigation of the Branimycin Stereochemistry at Position 17-C // Organic letters, 18 (2016), 4; 780-783 doi:10.1021/acs.orglett.6b00044 (međunarodna recenzija, članak, znanstveni)
CROSBI ID: 1003528 Za ispravke kontaktirajte CROSBI podršku putem web obrasca
Naslov
Reinvestigation of the Branimycin Stereochemistry at Position 17-C
Autori
Čikoš, Ana ; Triballeau, Nicolas ; Hubbard, Paul A. ; Žiher, Dinko ; Stouten, Pieter F. W. ; Doyon, Julien G. P.-O. ; Deschrijver, Tiny ; Wouters, Johan ; Lépine, Renaud H. M. ; Saniere, Laurent
Izvornik
Organic letters (1523-7060) 18
(2016), 4;
780-783
Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni
Ključne riječi
branimycin, stereochemistry, NMR
Sažetak
A conformational study of branimycin was performed using single-crystal X-ray crystallography to characterize the solid-state form, while a combination of NMR spectroscopy and molecular modeling was employed to gain information about the solution structure. Comparison of the crystal structure with its solution counterpart showed no significant differences in conformation, confirming the relative rigidity of the tricyclic system. However, these experiments revealed that the formerly proposed stereochemistry of branimycin at 17-C should be revised.
Izvorni jezik
Engleski
Znanstvena područja
Kemija
Citiraj ovu publikaciju:
Časopis indeksira:
- Current Contents Connect (CCC)
- Web of Science Core Collection (WoSCC)
- Science Citation Index Expanded (SCI-EXP)
- Arts & Humanities Citation Index (A&HCI)
- SCI-EXP, SSCI i/ili A&HCI
- Scopus
- MEDLINE
- Nature Index
