Naslov
New Mononuclear Iron Complex: Synthesis, X-Ray Diffraction, Magnetization, X-Band and High-Field ESR Study

Autori
Muratović, Senada ; Žilić, Dijana ; Džolić, Zoran ; Cetina, Mario ; Pajić, Damir ; Krupskaya, Yulia ; Kataev, Vladislav ; Goriya, Yogesh ; Johnson, Magnus

Vrsta, podvrsta i kategorija rada
Sažeci sa skupova, sažetak, znanstveni

Izvornik
ECMolS 2018 - 2nd European Conference on Molecular Spintronics / - Peníscola, 2018, 125-125

Skup
2nd European Conference on Molecular Spintronics

Mjesto i datum
Peníscola, Španjolska, 21.10.2018. - 24.10.2018

Vrsta sudjelovanja
Poster

Vrsta recenzije
Međunarodna recenzija

Ključne riječi
Iron complex ; ESR spectroscopy ; High-field

Sažetak
Reaction of 2-hydroxy-6-methylpyridine (L) with iron(II) tetrafluoroborate results in the isolation of [FeL6](BF4)3 a mononuclear iron(III) octahedral complex. X -ray diffraction studies have confirmed the existence of iron (III). Polycrystalline sample of the complex has been investigated by X-ray diffraction, magnetization and electron spin resonance (HF-ESR) spectroscopy. Beside commercially available X-band ESR, we used also multi-frequency (up to 318 GHz) high-field (up to 16 T) HF-ESR spectroscopy (Fig. 1). The obtained results will be discussed in terms of magneto-structural correlations. [1, 2] [1] P. Gamez et al. Dalton Trans. 2009, 7845-7853 [2] L. Wang et al. Chem. Eur. J. 10.1002/chem.201705989

Izvorni jezik
Engleski

Znanstvena područja
Fizika, Kemija

POVEZANOST RADA