Pregled bibliografske jedinice broj: 952241
Tetra-μ-benzoato-κ8O:O'-bis[N, N'-diethylformamide-κO)dicopper(II)
Tetra-μ-benzoato-κ8O:O'-bis[N, N'-diethylformamide-κO)dicopper(II) // 25th Slovenian-Croatian Crystallographic Meeting 2017, Book Of Abstracts
Ljubljana, Slovenija, 2017. str. 7-7 (predavanje, međunarodna recenzija, sažetak, znanstveni)
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Naslov
Tetra-μ-benzoato-κ8O:O'-bis[N, N'-diethylformamide-κO)dicopper(II)
Autori
Meštrić, Aleksandar ; Judaš, Nenad
Vrsta, podvrsta i kategorija rada
Sažeci sa skupova, sažetak, znanstveni
Izvornik
25th Slovenian-Croatian Crystallographic Meeting 2017, Book Of Abstracts
/ - , 2017, 7-7
Skup
25th Slovenian-Croatian Crystallographic Meeting 2017
Mjesto i datum
Ljubljana, Slovenija, 14.06.2017. - 18.06.2017
Vrsta sudjelovanja
Predavanje
Vrsta recenzije
Međunarodna recenzija
Ključne riječi
copper complex
Sažetak
Copper(II) carboxylates are based on a robust dinuclear paddlewheel unit to which additional ligands are attached by coordinating at the apical positions. Their simple syntheses have made copper(II) carboxylates interesting for materials science, especially for constructing porous metal–organic frameworks. The ability of such molecules to form adducts through binding additional ligands, in one application leads to formation of metal-containing frameworks (MOFs). By reacting the N, N'-diethylformamide and tetra-μ-benzoato-κ8O:O'-dicopper(II) complexes we have succeded to isolate and determine the crystal and molecular structures of the tetra-μ-benzoato-κ8O:O'-bis[(N, N'-diethylformamide-κO)dicopper(II)] The structure of the compounds suggest guidelines to achieve supramolecular isostructurality, useful for the synthesis of multi-component metal-organic materials following a design based on solid solution.
Izvorni jezik
Engleski
Znanstvena područja
Kemija
