Pregled bibliografske jedinice broj: 950784
Tuning the Reactivity of Peroxo Anhydrides for Aromatic C–H Bond Oxidation
Tuning the Reactivity of Peroxo Anhydrides for Aromatic C–H Bond Oxidation // Journal of organic chemistry, 83 (2018), 17; 10070-10079 doi:10.1021/acs.joc.8b01392 (međunarodna recenzija, članak, znanstveni)
CROSBI ID: 950784 Za ispravke kontaktirajte CROSBI podršku putem web obrasca
Naslov
Tuning the Reactivity of Peroxo Anhydrides for Aromatic C–H Bond Oxidation
Autori
Pilevar, Afsaneh ; Hosseini, Abolfazl ; Šekutor, Marina ; Hausmann, Heike ; Becker, Jonathan ; Turke, Kevin ; Schreiner, Peter R.
Izvornik
Journal of organic chemistry (0022-3263) 83
(2018), 17;
10070-10079
Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni
Ključne riječi
cyclic peroxide ; C-H oxidation ; hydroxylation of arenes ; norbornane
Sažetak
Phenol moieties are key structural motifs in many areas of chemical research from polymers to pharmaceuticals. Herein, we report on the design and use of a structurally demanding cyclic peroxide (spiro[bicyclo[2.2.1]heptane-2, 4′-[1, 2]dioxolane]-3′, 5′-dione, P4) for the direct hydroxylation of aromatic substrates. The new peroxide benefits from high thermal stability and can be synthesized from readily available starting materials. The aromatic C–H oxidation using P4 exhibits generally good yields (up to 96%) and appreciable regioselectivities.
Izvorni jezik
Engleski
Znanstvena područja
Kemija
Napomena
This work was supported by Justus Liebig University.
Citiraj ovu publikaciju:
Časopis indeksira:
- Current Contents Connect (CCC)
- Web of Science Core Collection (WoSCC)
- Science Citation Index Expanded (SCI-EXP)
- SCI-EXP, SSCI i/ili A&HCI
- Scopus
- MEDLINE
