Naslov
Chalcogen Bonding in Supramolecular Assemblies of Coordination Polymers of Cadmium(II)

Autori
Đaković, Marijana ; Penić, Nikolina ; Matijaković Nives

Vrsta, podvrsta i kategorija rada
Sažeci sa skupova, sažetak, znanstveni

Izvornik
Interactions Involving Group 14 ‐ 16 Elements as Electrophilic Sites: A World Parallel to Halogen Bond, Book of Abstracts / - , 2018, 50-50

Skup
Interactions Involving Group 14 ‐ 16 Elements as Electrophilic Sites: A World Parallel to Halogen Bond

Mjesto i datum
Greenville (SC), Sjedinjene Američke Države, 09.06.2018. - 10.06.2018

Vrsta sudjelovanja
Poster

Vrsta recenzije
Međunarodna recenzija

Ključne riječi
chalcogen interactions ; cadmium(II) ; thyocianate

Sažetak
Following the recent recognition of halogen bonding as an important structure-directing force in many coordination complexes, there is considerable interest in exploring and understanding related interactions involving electrophilic sites of main group elements (including chalcogens and pnictogens). In order to develop new synthetic avenues for the reliable construction of robust 1-D metal-containing building units [1-3], we have now started to examine if chalcogen bonds are capable of producing 1-D coordination polymers analogous to those structures that have been built with halogen- and hydrogen-bonds as synthetic vectors. In this contribution, we describe the structures of several thiocyanate complexes of cadmium(II) with small pyridine-type ligands, where chalcogen bonds seem to play important roles in the supramolecular assembly of 1-D coordination polymersOur new structural data are further explained within the context of information retrieved by extensive data mining of the CSD.

Izvorni jezik
Engleski

Znanstvena područja
Kemija

POVEZANOST RADA