Naslov
Building metal-organic architectures by the design

Autori
Đaković, Marijana ; Borovina, Mladen ; Aakeröy ; Kodrin, Ivan

Vrsta, podvrsta i kategorija rada
Sažeci sa skupova, sažetak, znanstveni

Izvornik
26th Annual Meeting of the German Crystallographic Society (DGK), Book of Abstracts ; dodatak časopisu Zeitschrift für Kristallographie / - , 2018, 37-37

Skup
26th Annual Meeting of the German Crystallographic Society (DGK 2018)

Mjesto i datum
Essen, Njemačka, 05.03.2018. - 08.03.2018

Vrsta sudjelovanja
Predavanje

Vrsta recenzije
Podatak o recenziji nije dostupan

Ključne riječi
supramolecular architectures ; metal-organic complexes ; MEP ; hydrogen bonds
(supramolecular architectures ; metal-organic complexes ; MEP ; hydrogen bond)

Sažetak
One of the primary challenges of crystal engineering is to deliver solids with a targeted physical property or response. As performance and properties of solid materials can be directly modified by controlling the nature of the 3-D assembly of molecules/ions, the first step towards a targeted property/response requires control over specific structural topologies. Unfortunately, a lack of robust and transferable guidelines for pre-planned synthesis based on non-covalent interactions still stands in the way of predicatable supramolecular assemblies of metal-containing solids. In this contribution we present our attempts and success in controlling the supramolecular assembly of metal-complexes (of various dimensionalities) via fine-tuning the strength of hydrogen- and halogen-bond donors and acceptors. The use of calculated molecular electrostatic potential surfaces for ranking potential donors and acceptors in the system is shown to be a useful method for achieveing the desired supramolecular outcome.

Izvorni jezik
Engleski

Znanstvena područja
Kemija

POVEZANOST RADA