Controlling Orthogonal Self-Assembly through Cis-Trans Isomerization of a Non-Covalent Palladium Complex Dimer

Kokan, Zoran; Kovačević, Borislav; Štefanić, Zoran; Tzvetkova, Pavleta; Kirin, Srećko I.

doi:10.1039/C7CC09537F

Pregled bibliografske jedinice broj: 916168

Controlling Orthogonal Self-Assembly through Cis-Trans Isomerization of a Non-Covalent Palladium Complex Dimer

Kokan, Zoran; Kovačević, Borislav; Štefanić, Zoran; Tzvetkova, Pavleta; Kirin, Srećko I.

Controlling Orthogonal Self-Assembly through Cis-Trans Isomerization of a Non-Covalent Palladium Complex Dimer // Chemical communications, 54 (2018), 17; 2094-2097 doi:10.1039/C7CC09537F (međunarodna recenzija, članak, znanstveni)

CROSBI ID: 916168 Za ispravke kontaktirajte CROSBI podršku putem web obrasca

Naslov
Controlling Orthogonal Self-Assembly through Cis-Trans Isomerization of a Non-Covalent Palladium Complex Dimer

Autori
Kokan, Zoran ; Kovačević, Borislav ; Štefanić, Zoran ; Tzvetkova, Pavleta ; Kirin, Srećko I.

Izvornik
Chemical communications (1359-7345) 54 (2018), 17; 2094-2097

Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni

Ključne riječi
dichloropalladium ; chiral ; self-assembly

Sažetak
The trans-configured square-planar complex of dichloropalladium and chiral monodentate phosphine ligands forms self-complementary dimers through 16 hydrogen bonded amides and π- π stacking in chlorinated solvents. The self- assembly is controled by cis-trans isomerisation of the metal center, where trans- configuration governs the dimer formation.

Izvorni jezik
Engleski

Znanstvena područja
Kemija

POVEZANOST RADA

Projekti:
HRZZ-IP-2014-09-1461 - Minimalni umjetni enzimi: Proširenje primjene posredne indukcije na nove supstrate i nove asimetrične reakcije (MArtEn) (Kirin, Srećko, HRZZ - 2014-09) ( CroRIS)

Ustanove:
Institut "Ruđer Bošković", Zagreb

Profili:

Zoran Kokan (autor)